Proton Transfer in the Catalytic Cycle of [NiFe] Hydrogenases: Insight from Vibrational Spectroscopy

por Ash, Philip A., Hidalgo, Ricardo, Vincent, Kylie A.
Publicado 2017

Protein Film Infrared Electrochemistry Demonstrated for Study of H(2) Oxidation by a [NiFe] Hydrogenase

por Ash, Philip A., Hidalgo, Ricardo, Vincent, Kylie A.
Publicado 2017

Electrochemical experiments define potentials associated with binding of substrates and inhibitors to nitrogenase MoFe protein

por Chen, Ting, Ash, Philip A., Seefeldt, Lance C., Vincent, Kylie A.
Publicado 2023

Infrared Spectroscopy During Electrocatalytic Turnover Reveals the Ni-L Active Site State During H(2) Oxidation by a NiFe Hydrogenase**

por Hidalgo, Ricardo, Ash, Philip A, Healy, Adam J, Vincent, Kylie A
Publicado 2015

Electrochemical control of [FeFe]-hydrogenase single crystals reveals complex redox populations at the catalytic site

por Morra, Simone, Duan, Jifu, Winkler, Martin, Ash, Philip A., Happe, Thomas, Vincent, Kylie A.
Publicado 2021

Electrochemical CO Oxidation at Platinum on Carbon Studied through Analysis of Anomalous in Situ IR Spectra

por McPherson, Ian J., Ash, Philip A., Jones, Lewys, Varambhia, Aakash, Jacobs, Robert M. J., Vincent, Kylie A.
Publicado 2017

Enzymes as modular catalysts for redox half-reactions in H(2)-powered chemical synthesis: from biology to technology

por Reeve, Holly A., Ash, Philip A., Park, HyunSeo, Huang, Ailun, Posidias, Michalis, Tomlinson, Chloe, Lenz, Oliver, Vincent, Kylie A.
Publicado 2017

Discovery of Dark pH-Dependent H(+) Migration in a [NiFe]-Hydrogenase and Its Mechanistic Relevance: Mobilizing the Hydrido Ligand of the Ni-C Intermediate

por Murphy, Bonnie J., Hidalgo, Ricardo, Roessler, Maxie M., Evans, Rhiannon M., Ash, Philip A., Myers, William K., Vincent, Kylie A., Armstrong, Fraser A.
Publicado 2015

Comprehensive structural, infrared spectroscopic and kinetic investigations of the roles of the active-site arginine in bidirectional hydrogen activation by the [NiFe]-hydrogenase...

por Evans, Rhiannon M., Beaton, Stephen E., Rodriguez Macia, Patricia, Pang, Yunjie, Wong, Kin Long, Kertess, Leonie, Myers, William K., Bjornsson, Ragnar, Ash, Philip A., Vincent, Kylie A., Carr, Stephen B., Armstrong, Fraser A.
Publicado 2023

The crystalline state as a dynamic system: IR microspectroscopy under electrochemical control for a [NiFe] hydrogenase

por Ash, Philip A., Kendall-Price, Sophie E. T., Evans, Rhiannon M., Carr, Stephen B., Brasnett, Amelia R., Morra, Simone, Rowbotham, Jack S., Hidalgo, Ricardo, Healy, Adam J., Cinque, Gianfelice, Frogley, Mark D., Armstrong, Fraser A., Vincent, Kylie A.
Publicado 2021

Synchrotron-Based Infrared Microanalysis of Biological Redox Processes under Electrochemical Control

por Ash, Philip A., Reeve, Holly A., Quinson, Jonathan, Hidalgo, Ricardo, Zhu, Tianze, McPherson, Ian J., Chung, Min-Wen, Healy, Adam J., Nayak, Simantini, Lonsdale, Thomas H., Wehbe, Katia, Kelley, Chris S., Frogley, Mark D., Cinque, Gianfelice, Vincent, Kylie A.
Publicado 2016