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Organic structural spectroscopy /
| Otros Autores: | |
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| Formato: | Libro |
| Lenguaje: | English |
| Publicado: |
Upper Saddle River, N.J. :
Pearson Prentice Hall,
c2011.
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| Edición: | 2nd ed. |
| Materias: |
Tabla de Contenidos:
- The Chemical Shift ; Factors That Influence Proton Shifts ; Proton Chemical Shifts and Structure ; Medium and Isotope Effects ; Factors That Influence Carbon Shirts ; Carbon Chemical Shifts and Structure ; Tables of Chemical Shifts
- Chapter 4 The Coupling Constant ; First-Order Spectra ; Chemical and Magnetic Equivalence ; Signs and Mechanisms ; Couplings over One Bond ; Geminal Couplings ; Vicinal Couplings ; Long-Range Couplings ; Spectral Analysis ; Second-Order Spectra ; Tables of Coupling Constants
- Chapter 5 Further Topics in One-Dimensional NMR ; Spin-Lattice and Spin-Spin Relaxation ; Reactions on the NMR Time Scale ; Multiple Resonance ; The Nuclear Overhauser Effect ; Spectral Editing ; Sensitivity Enhancement ; Carbon Connectivity ; Phase Cycling, Composite Pulses, and Shaped Pulses
- Chapter 6 Two-Dimensional NMR ; Proton-Proton Correlation Through Coupling ; Proton-Heteronucleus Correlation ; Proton-Proton Correlation Through Space or Chemical Exchange ; Carbon-Carbon Correlation ; Higher Dimensions ; Pulsed Field Gradients ; Summary of Two-Dimensional Methods
- Chapter 7 Instrumentation and Theory ; Ionization Methods ; Mass Analysis ; Chapter 8 Ion Activation and Fragmentation ; Basic Principles ; Methods and Energetics ; Functional Groups ; Chapter 9 Structural Analysis ; Molecular Weights ; Molecular Formula ; Structures from Fragmentation Patterns ; Polymers ; Chapter 10 Quantitative Applications ; Quantification of Analytes ; Thermochemistry ; Chapter 11 Introduction ; Vibrations of Molecules ; Infrared and Raman Spectra ; Units and Notation ; Infrared Spectra: Dispersive and Fourier Transform ; Sampling Methods for Infrared Transmission Spectra ; Raman Spectroscopy ; Raman Sampling Methods ; Depolarization Measurements ; Infrared Reflection Spectroscopy ; Chapter 12 Group Frequencies ; Factors Affecting Group Frequencies ; Infrared Group Frequencies ; Raman Group Frequencies ; Preliminary Analysis ; The CH Stretching Region (3340-2700 cm-1) ; The Carbonyl Stretching Region (1850-1650 cm-1) ; Aromatic Compounds ; Compounds Containing Methyl Groups ; Compounds Containing Methylene Groups ; Unsaturated Compounds ; Compounds Containing Oxygen ; Compounds Containing Nitrogen ; Compounds Containing Phosphorus and Sulfur ; Heterocyclic Compounds ; Compounds Containing Halogens ; Boron, Silicon, Tin, Lead, and Mercury Compounds ; Isotopically Labeled Compounds ; Using the Literature on Vibrational Spectroscopy Problems Bibliography ; Chapter 13 Introduction and Experimental Methods ; Measurement of Ultraviolet-Visible Light Absorption ; Quantitative Measurements ; Electronic Transitions ; Experimental Aspects ; Chapter 14 Structural Analysis ; Isolated Chromophores ; Conjugated Chromophores ; Aromatic Compounds ; Important Naturally Occurring Chromophores ; The Woodward-Fieser Rules ; Steric Effects ; Solvent Effects and Dynamic Equilibria ; Hydrogen Bonding Studies ; Homoconjugation ; Charge Transfer Band