Green organic chemistry : strategies, tools, and laboratory experiments

Detalles Bibliográficos
Autor principal: Doxsee, Kenneth M.
Otros Autores: Hutchison, James E.
Formato: Libro
Lenguaje:English
Publicado: Southbank, Vic., Australia ; Estados Unidos : Thomson-Brooks/Cole, ©2004.
Materias:
Química > Laboratorios
Química orgánica
Química del medio ambiente
Tabla de Contenidos:
  • Graphical Abstracts for the Experiments 13
  • Strategies and Tools
  • Chapter 2 Identification and Evaluation of Chemical Hazards 25
  • Chapter 3 Chemical Exposure and Environmental Contamination 35
  • Chapter 4 Sources of Information about Chemical Hazards 43
  • Chapter 5 Introduction to Green Chemistry 49
  • Chapter 6 Alternative Solvents 55
  • Chapter 7 Alternative Reagents 79
  • Chapter 8 Reaction Design and Efficiency 89
  • Chapter 9 Alternative Feedstocks and Products 96
  • Chapter 10 The Big Picture and Green Chemistry Metrics 102
  • Laboratory Experiments
  • Experiment 1 Solventless Reactions: The Aldol Reaction 115
  • Experiment 2 Bromination of An Alkene: Preparation of Stilbene Dibromide 120
  • Experiment 3 A Greener Bromination of Stilbene 125
  • Experiment 4 Preparation and Distillation of Cyclohexene 129
  • Experiment 5 Synthesis and Recrystallization of Adipic Acid 135
  • Experiment 6 Oxidative Coupling of Alkynes: The Glaser-Eglinton-Hay Coupling 142
  • Experiment 7 Gas-Phase Synthesis, Column Chromatography and Visible Spectroscopy of 5,10,15,20-Tetraphenylporphyrin 152
  • Experiment 8 Microwave Synthesis of 5,10,15,20-Tetraphenylporphyrin 159
  • Experiment 9 Metallation of 5,10,15,20-Tetraphenylporphyrin 163
  • Experiment 10 Measuring Solvent Effects: Kinetics of Hydrolysis of tert-Butyl Chloride 167
  • Experiment 11 Molecular Mechanics Modeling 174
  • Experiment 12 Electrophilic Aromatic Iodination 182
  • Experiment 13 Palladium-Catalyzed Alkyne Coupling/Intramolecular Alkyne Addition: Natural Product Synthesis 189
  • Experiment 14 Resin-Based Oxidation Chemistry 197
  • Experiment 15 Carbonyl Chemistry: Thiamine-Mediated Benzoin Condensation of Furfural 201
  • Experiment 16 Solid-Phase Photochemistry 206
  • Experiment 17 Applications of Organic Chemistry: Patterning Surfaces With Molecular Films 211
  • Experiment 18 The Friedel-Crafts Reaction: Acetylation of Ferrocene 225
  • Experiment 19 Combinatorial Chemistry: Antibiotic Drug Discovery 231
  • Appendix A The Twelve Principles of Green Chemistry 239.

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