The effect of moderators on the reactions of hot hydrogen atoms with methane

The reaction of recoil tritium with methane has been examined in further detail. The previous hypothesis that this system involves a hot displacement reaction of high kinetic energy hydrogen to give CH$_{3}$T, CH$_{2}$T and HT is confirmed. The effect of moderator on this process is studied by the a...

Descripción completa

Detalles Bibliográficos
Autores principales: Estrup, Peder J., Wolfgang, Richard
Publicado: 1960
Materias:
Chemical Physics and Chemistry
Acceso en línea:https://dx.doi.org/10.1021/ja01496a001
http://cds.cern.ch/record/2259446
_version_ 1780953933857947648
author Estrup, Peder J.
Wolfgang, Richard
author_facet Estrup, Peder J.
Wolfgang, Richard
author_sort Estrup, Peder J.
collection CERN
description The reaction of recoil tritium with methane has been examined in further detail. The previous hypothesis that this system involves a hot displacement reaction of high kinetic energy hydrogen to give CH$_{3}$T, CH$_{2}$T and HT is confirmed. The effect of moderator on this process is studied by the addition of noble gases. As predicted these gases inhibit the hot reaction action, their efficiency in this respect being He > Ne > A > Se. The data are quantitatively in accord with a theory of hot atom kinetics. The mechanism of the hot displacement process is briefly discussed.
id cern-2259446
institution Organización Europea para la Investigación Nuclear
publishDate 1960
record_format invenio
spelling cern-22594462019-09-30T06:29:59Zdoi:10.1021/ja01496a001http://cds.cern.ch/record/2259446Estrup, Peder J.Wolfgang, RichardThe effect of moderators on the reactions of hot hydrogen atoms with methaneChemical Physics and ChemistryThe reaction of recoil tritium with methane has been examined in further detail. The previous hypothesis that this system involves a hot displacement reaction of high kinetic energy hydrogen to give CH$_{3}$T, CH$_{2}$T and HT is confirmed. The effect of moderator on this process is studied by the addition of noble gases. As predicted these gases inhibit the hot reaction action, their efficiency in this respect being He > Ne > A > Se. The data are quantitatively in accord with a theory of hot atom kinetics. The mechanism of the hot displacement process is briefly discussed.oai:cds.cern.ch:22594461960
spellingShingle Chemical Physics and Chemistry
Estrup, Peder J.
Wolfgang, Richard
The effect of moderators on the reactions of hot hydrogen atoms with methane
title The effect of moderators on the reactions of hot hydrogen atoms with methane
title_full The effect of moderators on the reactions of hot hydrogen atoms with methane
title_fullStr The effect of moderators on the reactions of hot hydrogen atoms with methane
title_full_unstemmed The effect of moderators on the reactions of hot hydrogen atoms with methane
title_short The effect of moderators on the reactions of hot hydrogen atoms with methane
title_sort effect of moderators on the reactions of hot hydrogen atoms with methane
topic Chemical Physics and Chemistry
url https://dx.doi.org/10.1021/ja01496a001
http://cds.cern.ch/record/2259446
work_keys_str_mv AT estruppederj theeffectofmoderatorsonthereactionsofhothydrogenatomswithmethane
AT wolfgangrichard theeffectofmoderatorsonthereactionsofhothydrogenatomswithmethane
AT estruppederj effectofmoderatorsonthereactionsofhothydrogenatomswithmethane
AT wolfgangrichard effectofmoderatorsonthereactionsofhothydrogenatomswithmethane

Ejemplares similares