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Homochiral growth through enantiomeric cross-inhibition

The stability and conservation properties of a recently proposed polymerization model are studied. The achiral (racemic) solution is linearly unstable once the relevant control parameter (here the fidelity of the catalyst) exceeds a critical value. The growth rate is calculated for different fidelit...

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Detalles Bibliográficos
Autores principales: Brandenburg, A, Andersen, A C, Höfner, S, Nilsson, M
Lenguaje:eng
Publicado: 2004
Materias:
XX
Acceso en línea:http://cds.cern.ch/record/745758
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author Brandenburg, A
Andersen, A C
Höfner, S
Nilsson, M
author_facet Brandenburg, A
Andersen, A C
Höfner, S
Nilsson, M
author_sort Brandenburg, A
collection CERN
description The stability and conservation properties of a recently proposed polymerization model are studied. The achiral (racemic) solution is linearly unstable once the relevant control parameter (here the fidelity of the catalyst) exceeds a critical value. The growth rate is calculated for different fidelity parameters and cross-inhibition rates. A chirality parameter is defined and shown to be conserved by the nonlinear terms of the model. Finally, a truncated version of the model is used to derive a set of two ordinary differential equations and it is argued that these equations are more realistic than those used in earlier models of that form.
id cern-745758
institution Organización Europea para la Investigación Nuclear
language eng
publishDate 2004
record_format invenio
spelling cern-7457582019-09-30T06:29:59Zhttp://cds.cern.ch/record/745758engBrandenburg, AAndersen, A CHöfner, SNilsson, MHomochiral growth through enantiomeric cross-inhibitionXXThe stability and conservation properties of a recently proposed polymerization model are studied. The achiral (racemic) solution is linearly unstable once the relevant control parameter (here the fidelity of the catalyst) exceeds a critical value. The growth rate is calculated for different fidelity parameters and cross-inhibition rates. A chirality parameter is defined and shown to be conserved by the nonlinear terms of the model. Finally, a truncated version of the model is used to derive a set of two ordinary differential equations and it is argued that these equations are more realistic than those used in earlier models of that form.oai:cds.cern.ch:7457582004-04-26
spellingShingle XX
Brandenburg, A
Andersen, A C
Höfner, S
Nilsson, M
Homochiral growth through enantiomeric cross-inhibition
title Homochiral growth through enantiomeric cross-inhibition
title_full Homochiral growth through enantiomeric cross-inhibition
title_fullStr Homochiral growth through enantiomeric cross-inhibition
title_full_unstemmed Homochiral growth through enantiomeric cross-inhibition
title_short Homochiral growth through enantiomeric cross-inhibition
title_sort homochiral growth through enantiomeric cross-inhibition
topic XX
url http://cds.cern.ch/record/745758
work_keys_str_mv AT brandenburga homochiralgrowththroughenantiomericcrossinhibition
AT andersenac homochiralgrowththroughenantiomericcrossinhibition
AT hofners homochiralgrowththroughenantiomericcrossinhibition
AT nilssonm homochiralgrowththroughenantiomericcrossinhibition