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Neutron scattering investigations of the properties of the x - T phase diagram of Rb sub 1 sub - sub x (NH sub 4) sub x I mixed crystals

The x - T phase diagram of Rb sub 1 sub - sub x (NH sub 4) sub x I is studied using samples with the ammonium concentration 0.01<x<0.77 over a wide temperature region of 15 to 300 K by neutron powder diffraction and inelastic incoherent neutron scattering. The results of powder diffraction stu...

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Detalles Bibliográficos
Autores principales: Smirnov, L S, Natkaniec, I, Savenko, B N
Lenguaje:eng
Publicado: 2002
Materias:
Acceso en línea:http://cds.cern.ch/record/747140
Descripción
Sumario:The x - T phase diagram of Rb sub 1 sub - sub x (NH sub 4) sub x I is studied using samples with the ammonium concentration 0.01<x<0.77 over a wide temperature region of 15 to 300 K by neutron powder diffraction and inelastic incoherent neutron scattering. The results of powder diffraction studies show that at low temperatures a phase transition from alpha-phase to beta-phase is observed at ammonium concentrations x = 0.50 and x = 0.66. Inelastic incoherent neutron scattering detects a region of the orientional glass state at ammonium concentrations 0.29<x,0.40