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The role of the ion-molecule and molecule-molecule interactions in the formation of the two-ion average force interaction potential
The effect of the ion-molecule and intermolecular interactions on the formation of inter-ion average force potentials is investigated within the framework of a classical ion-dipole model of electrolyte solutions. These potentials are shown to possess the Coulomb asymptotics at large distances while...
| Autores principales: | , , |
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| Lenguaje: | eng |
| Publicado: |
2002
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| Acceso en línea: | http://cds.cern.ch/record/747144 |
| _version_ | 1780904149713420288 |
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| author | Ajrian, E A Gruba, V D Sidorenko, S N |
| author_facet | Ajrian, E A Gruba, V D Sidorenko, S N |
| author_sort | Ajrian, E A |
| collection | CERN |
| description | The effect of the ion-molecule and intermolecular interactions on the formation of inter-ion average force potentials is investigated within the framework of a classical ion-dipole model of electrolyte solutions. These potentials are shown to possess the Coulomb asymptotics at large distances while in the region of mean distances they reveal creation and disintegration of solvent-shared ion pairs. The calculation results provide a qualitatively authentic physical picture which is experimentally observed in strong electrolytes solutions. In particular, an increased interaction between an ion and a molecule enhances formation of ion pairs in which the ions are separated by one solvent molecule |
| id | cern-747144 |
| institution | Organización Europea para la Investigación Nuclear |
| language | eng |
| publishDate | 2002 |
| record_format | invenio |
| spelling | cern-7471442019-09-30T06:29:59Zhttp://cds.cern.ch/record/747144engAjrian, E AGruba, V DSidorenko, S NThe role of the ion-molecule and molecule-molecule interactions in the formation of the two-ion average force interaction potentialOther Fields of PhysicsThe effect of the ion-molecule and intermolecular interactions on the formation of inter-ion average force potentials is investigated within the framework of a classical ion-dipole model of electrolyte solutions. These potentials are shown to possess the Coulomb asymptotics at large distances while in the region of mean distances they reveal creation and disintegration of solvent-shared ion pairs. The calculation results provide a qualitatively authentic physical picture which is experimentally observed in strong electrolytes solutions. In particular, an increased interaction between an ion and a molecule enhances formation of ion pairs in which the ions are separated by one solvent moleculeJINR-E11-2002-260oai:cds.cern.ch:7471442002 |
| spellingShingle | Other Fields of Physics Ajrian, E A Gruba, V D Sidorenko, S N The role of the ion-molecule and molecule-molecule interactions in the formation of the two-ion average force interaction potential |
| title | The role of the ion-molecule and molecule-molecule interactions in the formation of the two-ion average force interaction potential |
| title_full | The role of the ion-molecule and molecule-molecule interactions in the formation of the two-ion average force interaction potential |
| title_fullStr | The role of the ion-molecule and molecule-molecule interactions in the formation of the two-ion average force interaction potential |
| title_full_unstemmed | The role of the ion-molecule and molecule-molecule interactions in the formation of the two-ion average force interaction potential |
| title_short | The role of the ion-molecule and molecule-molecule interactions in the formation of the two-ion average force interaction potential |
| title_sort | role of the ion-molecule and molecule-molecule interactions in the formation of the two-ion average force interaction potential |
| topic | Other Fields of Physics |
| url | http://cds.cern.ch/record/747144 |
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