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Hydrogen absorption-desorption properties of UZr sub 0 sub . sub 2 sub 9 alloy
Hydrogen absorption-desorption properties of UZr sub 0 sub . sub 2 sub 9 alloy are investigated in detail at hydrogen pressures up to 0.4 MPa and over the temperature range of 300 to 723 K. It absorbs hydrogen up to 2.3 H atoms per F.U. (formula unit) by only one-step reaction and hence each desorpt...
Autores principales: | , , , |
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Lenguaje: | chi |
Publicado: |
2001
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Materias: | |
Acceso en línea: | http://cds.cern.ch/record/747931 |
_version_ | 1780904202868883456 |
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author | Shuai Mao Bing Su Yong Jun WangZhenHong Zhang Yi Tao |
author_facet | Shuai Mao Bing Su Yong Jun WangZhenHong Zhang Yi Tao |
author_sort | Shuai Mao Bing |
collection | CERN |
description | Hydrogen absorption-desorption properties of UZr sub 0 sub . sub 2 sub 9 alloy are investigated in detail at hydrogen pressures up to 0.4 MPa and over the temperature range of 300 to 723 K. It absorbs hydrogen up to 2.3 H atoms per F.U. (formula unit) by only one-step reaction and hence each desorption isotherm has a single plateau over nearly the whole hydrogen composition range. The enthalpy and entropy changes of the dissociation reaction are of -78.9 kJ centre dot mol sup - sup 1 H sub 2 and 205.3 J centre dot(K centre dot mol H sub 2) sup - sup 1 , respectively. The alloy shows high durability against powdering upon hydrogenation and may have good heat conductivity. It is predicted that UZr sub 0 sub . sub 2 sub 9 alloy may be a suitable material for tritium treatment and storage |
id | cern-747931 |
institution | Organización Europea para la Investigación Nuclear |
language | chi |
publishDate | 2001 |
record_format | invenio |
spelling | cern-7479312019-09-30T06:29:59Zhttp://cds.cern.ch/record/747931chiShuai Mao BingSu Yong JunWangZhenHongZhang Yi TaoHydrogen absorption-desorption properties of UZr sub 0 sub . sub 2 sub 9 alloyCondensed MatterHydrogen absorption-desorption properties of UZr sub 0 sub . sub 2 sub 9 alloy are investigated in detail at hydrogen pressures up to 0.4 MPa and over the temperature range of 300 to 723 K. It absorbs hydrogen up to 2.3 H atoms per F.U. (formula unit) by only one-step reaction and hence each desorption isotherm has a single plateau over nearly the whole hydrogen composition range. The enthalpy and entropy changes of the dissociation reaction are of -78.9 kJ centre dot mol sup - sup 1 H sub 2 and 205.3 J centre dot(K centre dot mol H sub 2) sup - sup 1 , respectively. The alloy shows high durability against powdering upon hydrogenation and may have good heat conductivity. It is predicted that UZr sub 0 sub . sub 2 sub 9 alloy may be a suitable material for tritium treatment and storageCAEP-0094oai:cds.cern.ch:7479312001 |
spellingShingle | Condensed Matter Shuai Mao Bing Su Yong Jun WangZhenHong Zhang Yi Tao Hydrogen absorption-desorption properties of UZr sub 0 sub . sub 2 sub 9 alloy |
title | Hydrogen absorption-desorption properties of UZr sub 0 sub . sub 2 sub 9 alloy |
title_full | Hydrogen absorption-desorption properties of UZr sub 0 sub . sub 2 sub 9 alloy |
title_fullStr | Hydrogen absorption-desorption properties of UZr sub 0 sub . sub 2 sub 9 alloy |
title_full_unstemmed | Hydrogen absorption-desorption properties of UZr sub 0 sub . sub 2 sub 9 alloy |
title_short | Hydrogen absorption-desorption properties of UZr sub 0 sub . sub 2 sub 9 alloy |
title_sort | hydrogen absorption-desorption properties of uzr sub 0 sub . sub 2 sub 9 alloy |
topic | Condensed Matter |
url | http://cds.cern.ch/record/747931 |
work_keys_str_mv | AT shuaimaobing hydrogenabsorptiondesorptionpropertiesofuzrsub0subsub2sub9alloy AT suyongjun hydrogenabsorptiondesorptionpropertiesofuzrsub0subsub2sub9alloy AT wangzhenhong hydrogenabsorptiondesorptionpropertiesofuzrsub0subsub2sub9alloy AT zhangyitao hydrogenabsorptiondesorptionpropertiesofuzrsub0subsub2sub9alloy |