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Berkeley Off-line Radioisotope Generator (BORG)
Development of chemical separations for the transactinides has traditionally been performed with longer-lived tracer activities purchased commercially. With these long-lived tracers, there is always the potential problem that the tracer atoms are not always in the same chemical form as the short-liv...
Autores principales: | , |
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Lenguaje: | eng |
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2001
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Acceso en línea: | http://cds.cern.ch/record/748244 |
_version_ | 1780904234421583872 |
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author | Sudowe, R Patin, J B |
author_facet | Sudowe, R Patin, J B |
author_sort | Sudowe, R |
collection | CERN |
description | Development of chemical separations for the transactinides has traditionally been performed with longer-lived tracer activities purchased commercially. With these long-lived tracers, there is always the potential problem that the tracer atoms are not always in the same chemical form as the short-lived atoms produced in on-line experiments. This problem is especially severe for elements in groups 4 and 5 of the periodic table, where hydrolysis is present. The long-lived tracers usually are stored with a complexing agent to prevent sorption or precipitation. Chemistry experiments performed with these long-lived tracers are therefore not analogous to those chemical experiments performed in on-line experiments. One way to eliminate the differences between off-line and on-line chemistry experiments is through the use of a sup 2 sup 5 sup 2 Cf fission fragment collection device. A sup 2 sup 5 sup 2 Cf fission fragment collection device has already been constructed [1]. This device is limited in its capabilities. A new fission fragment device would allow the study of the chemical properties of the homologues of the heaviest elements. This new device would be capable of producing fission fragments for fast gas chemistry and aqueous chemistry experiments, long-lived tracers for model system development and neutrons for neutron activation. Fission fragment activities produced in this way should have the same chemical form as those produced in Cyclotron irradiations. The simple operation of this source will allow more rapid and reliable development of radiochemical separations with homologues of transactinide elements. |
id | cern-748244 |
institution | Organización Europea para la Investigación Nuclear |
language | eng |
publishDate | 2001 |
record_format | invenio |
spelling | cern-7482442019-09-30T06:29:59Zhttp://cds.cern.ch/record/748244engSudowe, RPatin, J BBerkeley Off-line Radioisotope Generator (BORG)Nuclear PhysicsDevelopment of chemical separations for the transactinides has traditionally been performed with longer-lived tracer activities purchased commercially. With these long-lived tracers, there is always the potential problem that the tracer atoms are not always in the same chemical form as the short-lived atoms produced in on-line experiments. This problem is especially severe for elements in groups 4 and 5 of the periodic table, where hydrolysis is present. The long-lived tracers usually are stored with a complexing agent to prevent sorption or precipitation. Chemistry experiments performed with these long-lived tracers are therefore not analogous to those chemical experiments performed in on-line experiments. One way to eliminate the differences between off-line and on-line chemistry experiments is through the use of a sup 2 sup 5 sup 2 Cf fission fragment collection device. A sup 2 sup 5 sup 2 Cf fission fragment collection device has already been constructed [1]. This device is limited in its capabilities. A new fission fragment device would allow the study of the chemical properties of the homologues of the heaviest elements. This new device would be capable of producing fission fragments for fast gas chemistry and aqueous chemistry experiments, long-lived tracers for model system development and neutrons for neutron activation. Fission fragment activities produced in this way should have the same chemical form as those produced in Cyclotron irradiations. The simple operation of this source will allow more rapid and reliable development of radiochemical separations with homologues of transactinide elements.oai:cds.cern.ch:7482442001-07-23 |
spellingShingle | Nuclear Physics Sudowe, R Patin, J B Berkeley Off-line Radioisotope Generator (BORG) |
title | Berkeley Off-line Radioisotope Generator (BORG) |
title_full | Berkeley Off-line Radioisotope Generator (BORG) |
title_fullStr | Berkeley Off-line Radioisotope Generator (BORG) |
title_full_unstemmed | Berkeley Off-line Radioisotope Generator (BORG) |
title_short | Berkeley Off-line Radioisotope Generator (BORG) |
title_sort | berkeley off-line radioisotope generator (borg) |
topic | Nuclear Physics |
url | http://cds.cern.ch/record/748244 |
work_keys_str_mv | AT sudower berkeleyofflineradioisotopegeneratorborg AT patinjb berkeleyofflineradioisotopegeneratorborg |