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Towards $^{31}$Mg-$\beta$-NMR resonance linewidths adequate for applications in magnesium chemistry
The span of most chemical shifts recorded in conventional $^{25}$Mg-NMR spectroscopy is $\sim$ 100 ppm. Accordingly, linewidths of $\sim$ 10 ppm or better are desirable to achieve adequate resolution for applications in chemistry. Here we present first high-field $^{31}$Mg- $\beta$-NMR measurements...
| Autores principales: | , , , , , , , , , , , , , , , , , , , |
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| Lenguaje: | eng |
| Publicado: |
2017
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| Materias: | |
| Acceso en línea: | https://dx.doi.org/10.1007/s10751-017-1408-8 http://cds.cern.ch/record/2318782 |
| _version_ | 1780958453322219520 |
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| author | Stachura, M McFadden, R M L Chatzichristos, A Dehn, M H Gottberg, A Hemmingsen, L Jancso, A Karner, V L Kiefl, R F Larsen, F H Lassen, J Levy, C D P Li, R MacFarlane, W A Morris, G D Pallada, S Pearson, M R Szunyogh, D Thulstrup, P W Voss, A |
| author_facet | Stachura, M McFadden, R M L Chatzichristos, A Dehn, M H Gottberg, A Hemmingsen, L Jancso, A Karner, V L Kiefl, R F Larsen, F H Lassen, J Levy, C D P Li, R MacFarlane, W A Morris, G D Pallada, S Pearson, M R Szunyogh, D Thulstrup, P W Voss, A |
| author_sort | Stachura, M |
| collection | CERN |
| description | The span of most chemical shifts recorded in conventional $^{25}$Mg-NMR spectroscopy is $\sim$ 100 ppm. Accordingly, linewidths of $\sim$ 10 ppm or better are desirable to achieve adequate resolution for applications in chemistry. Here we present first high-field $^{31}$Mg- $\beta$-NMR measurements of $^{31}$Mg$^+$ ions implanted into a MgO single crystal carried out at the ISAC facility at TRIUMF. The resonances recorded at 2.5 T and 3.5 T show strong linewidth dependency on the applied RF power, ranging from $\sim$ 419 ppm for the highest RF power down to $\sim$ 48 ppm for the lowest one. |
| id | oai-inspirehep.net-1673597 |
| institution | Organización Europea para la Investigación Nuclear |
| language | eng |
| publishDate | 2017 |
| record_format | invenio |
| spelling | oai-inspirehep.net-16735972019-09-30T06:29:59Zdoi:10.1007/s10751-017-1408-8http://cds.cern.ch/record/2318782engStachura, MMcFadden, R M LChatzichristos, ADehn, M HGottberg, AHemmingsen, LJancso, AKarner, V LKiefl, R FLarsen, F HLassen, JLevy, C D PLi, RMacFarlane, W AMorris, G DPallada, SPearson, M RSzunyogh, DThulstrup, P WVoss, ATowards $^{31}$Mg-$\beta$-NMR resonance linewidths adequate for applications in magnesium chemistryChemical Physics and ChemistryThe span of most chemical shifts recorded in conventional $^{25}$Mg-NMR spectroscopy is $\sim$ 100 ppm. Accordingly, linewidths of $\sim$ 10 ppm or better are desirable to achieve adequate resolution for applications in chemistry. Here we present first high-field $^{31}$Mg- $\beta$-NMR measurements of $^{31}$Mg$^+$ ions implanted into a MgO single crystal carried out at the ISAC facility at TRIUMF. The resonances recorded at 2.5 T and 3.5 T show strong linewidth dependency on the applied RF power, ranging from $\sim$ 419 ppm for the highest RF power down to $\sim$ 48 ppm for the lowest one.oai:inspirehep.net:16735972017 |
| spellingShingle | Chemical Physics and Chemistry Stachura, M McFadden, R M L Chatzichristos, A Dehn, M H Gottberg, A Hemmingsen, L Jancso, A Karner, V L Kiefl, R F Larsen, F H Lassen, J Levy, C D P Li, R MacFarlane, W A Morris, G D Pallada, S Pearson, M R Szunyogh, D Thulstrup, P W Voss, A Towards $^{31}$Mg-$\beta$-NMR resonance linewidths adequate for applications in magnesium chemistry |
| title | Towards $^{31}$Mg-$\beta$-NMR resonance linewidths adequate for applications in magnesium chemistry |
| title_full | Towards $^{31}$Mg-$\beta$-NMR resonance linewidths adequate for applications in magnesium chemistry |
| title_fullStr | Towards $^{31}$Mg-$\beta$-NMR resonance linewidths adequate for applications in magnesium chemistry |
| title_full_unstemmed | Towards $^{31}$Mg-$\beta$-NMR resonance linewidths adequate for applications in magnesium chemistry |
| title_short | Towards $^{31}$Mg-$\beta$-NMR resonance linewidths adequate for applications in magnesium chemistry |
| title_sort | towards $^{31}$mg-$\beta$-nmr resonance linewidths adequate for applications in magnesium chemistry |
| topic | Chemical Physics and Chemistry |
| url | https://dx.doi.org/10.1007/s10751-017-1408-8 http://cds.cern.ch/record/2318782 |
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