Cargando…

Unravelling the Mechanism and Governing Factors in Lewis Acid and Non-Covalent Diels–Alder Catalysis: Different Perspectives

In the current literature, many non-covalent interaction (NCI) donors have been proposed that can potentially catalyze Diels-Alder (DA) reactions. In this study, a detailed analysis of the governing factors in Lewis acid and non-covalent catalysis of three types of DA reactions was carried out, for...

Descripción completa

Detalles Bibliográficos
Autores principales:	Vermeersch, Lise, De Proft, Frank, Faulkner, Vicky, De Vleeschouwer, Freija
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2023
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10003447/ https://www.ncbi.nlm.nih.gov/pubmed/36902369 http://dx.doi.org/10.3390/ijms24054938

Ejemplares similares

Hydrogen-Bond-Assisted Diels–Alder Kinetics or Self-Healing in Reversible Polymer Networks? A Combined Experimental and Theoretical Study
por: Mangialetto, Jessica, et al.
Publicado: (2022)

Origin of Catalysis and Selectivity in Lewis Acid-Promoted Diels–Alder Reactions Involving Vinylazaarenes as Dienophiles
por: Portela, Susana, et al.
Publicado: (2022)

How Lewis Acids Catalyze Diels–Alder Reactions
por: Vermeeren, Pascal, et al.
Publicado: (2020)

Heterolytic Splitting of Molecular Hydrogen by Frustrated and Classical Lewis Pairs: A Unified Reactivity Concept
por: Skara, Gabriella, et al.
Publicado: (2017)

Vinylazaarenes as dienophiles in Lewis acid-promoted Diels–Alder reactions
por: Davis, Anna E., et al.
Publicado: (2021)

Enantioselective Diels–Alder reaction of anthracene by chiral tritylium catalysis
por: Zhang, Qichao, et al.
Publicado: (2019)

Asymmetric pyrone Diels–Alder reactions enabled by dienamine catalysis
por: Cole, Charles J. F., et al.
Publicado: (2019)

Toward Understanding CB[7]-Based Supramolecular Diels-Alder Catalysis
por: Berta, Dénes, et al.
Publicado: (2020)

An MM and QM Study of Biomimetic Catalysis of Diels-Alder Reactions Using Cyclodextrins
por: Chen, Wei, et al.
Publicado: (2018)

Roles of Lewis Acid Catalysts in Diels‐Alder Reactions between Cyclopentadiene and Methyl Acrylate
por: Sakata, Ken, et al.
Publicado: (2020)

Lewis Acid‐Catalyzed Diels‐Alder Reactions: Reactivity Trends across the Periodic Table
por: Vermeeren, Pascal, et al.
Publicado: (2021)

Orthogonal Catalysis for an Enantioselective Domino Inverse‐Electron Demand Diels−Alder/Substitution Reaction
por: Beeck, Sebastian, et al.
Publicado: (2021)

The hexadehydro-Diels–Alder reaction
por: Hoye, Thomas R., et al.
Publicado: (2012)

The pentadehydro-Diels–Alder reaction
por: Wang, Teng, et al.
Publicado: (2016)

An on‐surface Diels–Alder reaction
por: Castro‐Esteban, Jesús, et al.
Publicado: (2021)

Intramolecular Diels–Alder Reactions of Cycloalkenones: Stereoselectivity, Lewis Acid Acceleration, and Halogen Substituent Effects
por: Pham, Hung V., et al.
Publicado: (2014)

Unveiling the Lewis Acid Catalyzed Diels–Alder Reactions Through the Molecular Electron Density Theory
por: Domingo, Luis R., et al.
Publicado: (2020)

Diels–Alder reactions in confined spaces: the influence of catalyst structure and the nature of active sites for the retro-Diels–Alder reaction
por: Cantín, Ángel, et al.
Publicado: (2016)

Hierarchically assembled helicates as reaction platform – from stoichiometric Diels–Alder reactions to enamine catalysis
por: Van Craen, David, et al.
Publicado: (2020)

η(6)‐Metalated Aryl Iodides in Diels‐Alder Cycloaddition Reactions: Mode of Activation and Catalysis
por: Portela, Susana, et al.
Publicado: (2022)

Origin of asynchronicity in Diels–Alder reactions
por: Vermeeren, Pascal, et al.
Publicado: (2021)

Dual Activation of Aromatic Diels–Alder Reactions
por: Narsaria, Ayush K., et al.
Publicado: (2019)

Diels–Alder Reactions During the Biosynthesis of Sorbicillinoids
por: Kahlert, Lukas, et al.
Publicado: (2020)

Diels–Alder Cycloaddition Reactions in Sustainable Media
por: Soares, Maria I. L., et al.
Publicado: (2022)

The simplest Diels–Alder reactions are not endo-selective
por: Lording, William J., et al.
Publicado: (2020)

How Ionization Catalyzes Diels‐Alder Reactions
por: Vermeeren, Pascal, et al.
Publicado: (2022)

Enantioselective oxa‐Diels–Alder Sequences of Dendralenes
por: Fan, Yi‐Min, et al.
Publicado: (2022)

How Bases Catalyze Diels‐Alder Reactions
por: Yu, Song, et al.
Publicado: (2022)

Switch From Pauli‐Lowering to LUMO‐Lowering Catalysis in Brønsted Acid‐Catalyzed Aza‐Diels‐Alder Reactions
por: Yu, Song, et al.
Publicado: (2021)

A Combined Experimental/Quantum-Chemical Study of Tetrel, Pnictogen, and Chalcogen Bonds of Linear Triatomic Molecules
por: De Vleeschouwer, Freija, et al.
Publicado: (2021)

High stereoselectivity on low temperature Diels-Alder reactions
por: da Silva Filho, Luiz Carlos, et al.
Publicado: (2005)

Acylammonium Salts as Dienophiles in Diels–Alder/Lactonization Organocascades
por: Abbasov, Mikail E., et al.
Publicado: (2014)

A versatile Diels–Alder approach to functionalized hydroanthraquinones
por: Beck, Janina, et al.
Publicado: (2020)

Dual-Wavelength Gated oxo-Diels–Alder Photoligation
por: Villabona, Marc, et al.
Publicado: (2021)

Alkylhalovinylboranes: a new class of Diels–Alder dienophiles
por: Pisano, Pablo L., et al.
Publicado: (2018)

Cross-Linking of Polypropylene via the Diels–Alder Reaction
por: Muljana, Henky, et al.
Publicado: (2022)

Radical cation Diels–Alder reactions of arylidene cycloalkanes
por: Nakayama, Kaii, et al.
Publicado: (2022)

Ultramicroporous Polyphenylenes via Diels–Alder Polycondensation Approach
por: Sorokina, Svetlana A., et al.
Publicado: (2023)

Base-promoted cascade β-F-elimination/electrocyclization/Diels–Alder/retro-Diels–Alder reaction: efficient access to δ-carboline derivatives
por: Sun, Xi-Shang, et al.
Publicado: (2022)

Catalysis of a Diels–Alder Reaction between Azachalcones and Cyclopentadiene by a Recyclable Copper(II)-PEIP Metal-Organic Framework
por: Hadjikyprianou, Eleni, et al.
Publicado: (2023)

Cannot write session to /tmp/vufind_sessions/sess_u1at6vco0b18fvsmtaj0mn4ffe