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Microstructure and Mechanical Characteristics of Ti-Ta Alloys before and after NaOH Treatment and Their Behavior in Simulated Body Fluid

In the present study, the microstructure and mechanical properties of Ti-xTa (x = 5%, 15%, and 25% wt. Ta) alloys produced by using an induced furnace by the cold crucible levitation fusion technique were investigated and compared. The microstructure was examined by scanning electron microscopy and...

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Autores principales: Hulka, Iosif, Mirza-Rosca, Julia Claudia, Buzdugan, Dragos, Saceleanu, Adriana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10003825/
https://www.ncbi.nlm.nih.gov/pubmed/36903057
http://dx.doi.org/10.3390/ma16051943
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author Hulka, Iosif
Mirza-Rosca, Julia Claudia
Buzdugan, Dragos
Saceleanu, Adriana
author_facet Hulka, Iosif
Mirza-Rosca, Julia Claudia
Buzdugan, Dragos
Saceleanu, Adriana
author_sort Hulka, Iosif
collection PubMed
description In the present study, the microstructure and mechanical properties of Ti-xTa (x = 5%, 15%, and 25% wt. Ta) alloys produced by using an induced furnace by the cold crucible levitation fusion technique were investigated and compared. The microstructure was examined by scanning electron microscopy and X-ray diffraction. The alloys present a microstructure characterized by the α′ lamellar structure in a matrix of the transformed β phase. From the bulk materials, the samples for the tensile tests were prepared and based on the results and the elastic modulus was calculated by deducting the lowest values for the Ti-25Ta alloy. Moreover, a surface alkali treatment functionalization was performed using 10 M NaOH. The microstructure of the new developed films on the surface of the Ti-xTa alloys was investigated by scanning electron microscopy and the chemical analysis revealed the formation of sodium titanate and sodium tantanate along with titanium and tantalum oxides. Using low loads, the Vickers hardness test revealed increased hardness values for the alkali-treated samples. After exposure to simulated body fluid, phosphorus and calcium were identified on the surface of the new developed film, indicating the development of apatite. The corrosion resistance was evaluated by open cell potential measurements in simulated body fluid before and after NaOH treatment. The tests were performed at 22 °C as well as at 40 °C, simulating fever. The results show that the Ta content has a detrimental effect on the investigated alloys’ microstructure, hardness, elastic modulus, and corrosion behavior.
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spelling pubmed-100038252023-03-11 Microstructure and Mechanical Characteristics of Ti-Ta Alloys before and after NaOH Treatment and Their Behavior in Simulated Body Fluid Hulka, Iosif Mirza-Rosca, Julia Claudia Buzdugan, Dragos Saceleanu, Adriana Materials (Basel) Article In the present study, the microstructure and mechanical properties of Ti-xTa (x = 5%, 15%, and 25% wt. Ta) alloys produced by using an induced furnace by the cold crucible levitation fusion technique were investigated and compared. The microstructure was examined by scanning electron microscopy and X-ray diffraction. The alloys present a microstructure characterized by the α′ lamellar structure in a matrix of the transformed β phase. From the bulk materials, the samples for the tensile tests were prepared and based on the results and the elastic modulus was calculated by deducting the lowest values for the Ti-25Ta alloy. Moreover, a surface alkali treatment functionalization was performed using 10 M NaOH. The microstructure of the new developed films on the surface of the Ti-xTa alloys was investigated by scanning electron microscopy and the chemical analysis revealed the formation of sodium titanate and sodium tantanate along with titanium and tantalum oxides. Using low loads, the Vickers hardness test revealed increased hardness values for the alkali-treated samples. After exposure to simulated body fluid, phosphorus and calcium were identified on the surface of the new developed film, indicating the development of apatite. The corrosion resistance was evaluated by open cell potential measurements in simulated body fluid before and after NaOH treatment. The tests were performed at 22 °C as well as at 40 °C, simulating fever. The results show that the Ta content has a detrimental effect on the investigated alloys’ microstructure, hardness, elastic modulus, and corrosion behavior. MDPI 2023-02-26 /pmc/articles/PMC10003825/ /pubmed/36903057 http://dx.doi.org/10.3390/ma16051943 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Hulka, Iosif
Mirza-Rosca, Julia Claudia
Buzdugan, Dragos
Saceleanu, Adriana
Microstructure and Mechanical Characteristics of Ti-Ta Alloys before and after NaOH Treatment and Their Behavior in Simulated Body Fluid
title Microstructure and Mechanical Characteristics of Ti-Ta Alloys before and after NaOH Treatment and Their Behavior in Simulated Body Fluid
title_full Microstructure and Mechanical Characteristics of Ti-Ta Alloys before and after NaOH Treatment and Their Behavior in Simulated Body Fluid
title_fullStr Microstructure and Mechanical Characteristics of Ti-Ta Alloys before and after NaOH Treatment and Their Behavior in Simulated Body Fluid
title_full_unstemmed Microstructure and Mechanical Characteristics of Ti-Ta Alloys before and after NaOH Treatment and Their Behavior in Simulated Body Fluid
title_short Microstructure and Mechanical Characteristics of Ti-Ta Alloys before and after NaOH Treatment and Their Behavior in Simulated Body Fluid
title_sort microstructure and mechanical characteristics of ti-ta alloys before and after naoh treatment and their behavior in simulated body fluid
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10003825/
https://www.ncbi.nlm.nih.gov/pubmed/36903057
http://dx.doi.org/10.3390/ma16051943
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