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Kinetics of Catalytic Oxidation of Methylene Blue with La/Cu Co-Doped in Attapulgite
Methylene blue (MB) is a common pollutant in wastewater from the printing and dyeing industries. In this study, attapulgite (ATP) was modified with La(3+)/Cu(2+), using the method of equivolumetric impregnation. The La(3+)/Cu(2+) -ATP nanocomposites were characterized using X-ray diffraction (XRD) a...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10003998/ https://www.ncbi.nlm.nih.gov/pubmed/36903201 http://dx.doi.org/10.3390/ma16052087 |
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author | Shang, Jianping Zhang, Wei Dong, Zhengliang Fan, Hua-Jun Shawn |
author_facet | Shang, Jianping Zhang, Wei Dong, Zhengliang Fan, Hua-Jun Shawn |
author_sort | Shang, Jianping |
collection | PubMed |
description | Methylene blue (MB) is a common pollutant in wastewater from the printing and dyeing industries. In this study, attapulgite (ATP) was modified with La(3+)/Cu(2+), using the method of equivolumetric impregnation. The La(3+)/Cu(2+) -ATP nanocomposites were characterized using X-ray diffraction (XRD) and scanning electron microscopy (SEM). The catalytic properties of the modified ATP and the original ATP were compared. At the same time, the influence of the reaction temperature, concentration of methylene blue and pH on the reaction rate were investigated. The optimal reaction conditions are as follows: MB concentration is 80 mg/L, the dosage of the catalyst is 0.30 g, the dosage of hydrogen peroxide is 2 mL, the pH is 10 and the reaction temperature is 50 °C. Under these conditions, the degradation rate of MB can reach 98%. The recatalysis experiment was carried out reusing the catalyst, and the experimental results showed that the degradation rate could reach 65% after three uses, indicating that the catalyst could be recycled many times and costs could be reduced. Finally, the degradation mechanism of MB was speculated, and the reaction kinetic equation was obtained as follows: −dc/dt = 14,044 exp(−3598.34/T)C(O)(0.28). |
format | Online Article Text |
id | pubmed-10003998 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-100039982023-03-11 Kinetics of Catalytic Oxidation of Methylene Blue with La/Cu Co-Doped in Attapulgite Shang, Jianping Zhang, Wei Dong, Zhengliang Fan, Hua-Jun Shawn Materials (Basel) Article Methylene blue (MB) is a common pollutant in wastewater from the printing and dyeing industries. In this study, attapulgite (ATP) was modified with La(3+)/Cu(2+), using the method of equivolumetric impregnation. The La(3+)/Cu(2+) -ATP nanocomposites were characterized using X-ray diffraction (XRD) and scanning electron microscopy (SEM). The catalytic properties of the modified ATP and the original ATP were compared. At the same time, the influence of the reaction temperature, concentration of methylene blue and pH on the reaction rate were investigated. The optimal reaction conditions are as follows: MB concentration is 80 mg/L, the dosage of the catalyst is 0.30 g, the dosage of hydrogen peroxide is 2 mL, the pH is 10 and the reaction temperature is 50 °C. Under these conditions, the degradation rate of MB can reach 98%. The recatalysis experiment was carried out reusing the catalyst, and the experimental results showed that the degradation rate could reach 65% after three uses, indicating that the catalyst could be recycled many times and costs could be reduced. Finally, the degradation mechanism of MB was speculated, and the reaction kinetic equation was obtained as follows: −dc/dt = 14,044 exp(−3598.34/T)C(O)(0.28). MDPI 2023-03-03 /pmc/articles/PMC10003998/ /pubmed/36903201 http://dx.doi.org/10.3390/ma16052087 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Shang, Jianping Zhang, Wei Dong, Zhengliang Fan, Hua-Jun Shawn Kinetics of Catalytic Oxidation of Methylene Blue with La/Cu Co-Doped in Attapulgite |
title | Kinetics of Catalytic Oxidation of Methylene Blue with La/Cu Co-Doped in Attapulgite |
title_full | Kinetics of Catalytic Oxidation of Methylene Blue with La/Cu Co-Doped in Attapulgite |
title_fullStr | Kinetics of Catalytic Oxidation of Methylene Blue with La/Cu Co-Doped in Attapulgite |
title_full_unstemmed | Kinetics of Catalytic Oxidation of Methylene Blue with La/Cu Co-Doped in Attapulgite |
title_short | Kinetics of Catalytic Oxidation of Methylene Blue with La/Cu Co-Doped in Attapulgite |
title_sort | kinetics of catalytic oxidation of methylene blue with la/cu co-doped in attapulgite |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10003998/ https://www.ncbi.nlm.nih.gov/pubmed/36903201 http://dx.doi.org/10.3390/ma16052087 |
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