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Supported Ionic Liquid Phase Catalysts Dedicated for Continuous Flow Synthesis
Heterogeneous catalysis, although known for over a century, is constantly improved and plays a key role in solving the present problems in chemical technology. Thanks to the development of modern materials engineering, solid supports for catalytic phases having a highly developed surface are availab...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10004067/ https://www.ncbi.nlm.nih.gov/pubmed/36903221 http://dx.doi.org/10.3390/ma16052106 |
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author | Latos, Piotr Wolny, Anna Chrobok, Anna |
author_facet | Latos, Piotr Wolny, Anna Chrobok, Anna |
author_sort | Latos, Piotr |
collection | PubMed |
description | Heterogeneous catalysis, although known for over a century, is constantly improved and plays a key role in solving the present problems in chemical technology. Thanks to the development of modern materials engineering, solid supports for catalytic phases having a highly developed surface are available. Recently, continuous-flow synthesis started to be a key technology in the synthesis of high added value chemicals. These processes are more efficient, sustainable, safer and cheaper to operate. The most promising is the use of heterogeneous catalyst with column-type fixed-bed reactors. The advantages of the use of heterogeneous catalyst in continuous flow reactors are the physical separation of product and catalyst, as well as the reduction in inactivation and loss of the catalyst. However, the state-of-the-art use of heterogeneous catalysts in flow systems compared to homogenous ones remains still open. The lifetime of heterogeneous catalysts remains a significant hurdle to realise sustainable flow synthesis. The goal of this review article was to present a state of knowledge concerning the application of Supported Ionic Liquid Phase (SILP) catalysts dedicated for continuous flow synthesis. |
format | Online Article Text |
id | pubmed-10004067 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-100040672023-03-11 Supported Ionic Liquid Phase Catalysts Dedicated for Continuous Flow Synthesis Latos, Piotr Wolny, Anna Chrobok, Anna Materials (Basel) Review Heterogeneous catalysis, although known for over a century, is constantly improved and plays a key role in solving the present problems in chemical technology. Thanks to the development of modern materials engineering, solid supports for catalytic phases having a highly developed surface are available. Recently, continuous-flow synthesis started to be a key technology in the synthesis of high added value chemicals. These processes are more efficient, sustainable, safer and cheaper to operate. The most promising is the use of heterogeneous catalyst with column-type fixed-bed reactors. The advantages of the use of heterogeneous catalyst in continuous flow reactors are the physical separation of product and catalyst, as well as the reduction in inactivation and loss of the catalyst. However, the state-of-the-art use of heterogeneous catalysts in flow systems compared to homogenous ones remains still open. The lifetime of heterogeneous catalysts remains a significant hurdle to realise sustainable flow synthesis. The goal of this review article was to present a state of knowledge concerning the application of Supported Ionic Liquid Phase (SILP) catalysts dedicated for continuous flow synthesis. MDPI 2023-03-05 /pmc/articles/PMC10004067/ /pubmed/36903221 http://dx.doi.org/10.3390/ma16052106 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Review Latos, Piotr Wolny, Anna Chrobok, Anna Supported Ionic Liquid Phase Catalysts Dedicated for Continuous Flow Synthesis |
title | Supported Ionic Liquid Phase Catalysts Dedicated for Continuous Flow Synthesis |
title_full | Supported Ionic Liquid Phase Catalysts Dedicated for Continuous Flow Synthesis |
title_fullStr | Supported Ionic Liquid Phase Catalysts Dedicated for Continuous Flow Synthesis |
title_full_unstemmed | Supported Ionic Liquid Phase Catalysts Dedicated for Continuous Flow Synthesis |
title_short | Supported Ionic Liquid Phase Catalysts Dedicated for Continuous Flow Synthesis |
title_sort | supported ionic liquid phase catalysts dedicated for continuous flow synthesis |
topic | Review |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10004067/ https://www.ncbi.nlm.nih.gov/pubmed/36903221 http://dx.doi.org/10.3390/ma16052106 |
work_keys_str_mv | AT latospiotr supportedionicliquidphasecatalystsdedicatedforcontinuousflowsynthesis AT wolnyanna supportedionicliquidphasecatalystsdedicatedforcontinuousflowsynthesis AT chrobokanna supportedionicliquidphasecatalystsdedicatedforcontinuousflowsynthesis |