Cargando…

Surface-Dependent Hydrogen Evolution Activity of Copper Foil

Single-crystal planes are ideal platforms for catalytic research. In this work, rolled copper foils with predominantly (220) planes were used as the starting material. By using temperature gradient annealing, which caused grain recrystallization in the foils, they were transformed to those with (200...

Descripción completa

Detalles Bibliográficos
Autores principales: Kong, Ling-Jie, Hu, Xin-Zhuo, Chen, Chuan-Qi, Kulinich, Sergei A., Du, Xi-Wen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10004233/
https://www.ncbi.nlm.nih.gov/pubmed/36902893
http://dx.doi.org/10.3390/ma16051777
Descripción
Sumario:Single-crystal planes are ideal platforms for catalytic research. In this work, rolled copper foils with predominantly (220) planes were used as the starting material. By using temperature gradient annealing, which caused grain recrystallization in the foils, they were transformed to those with (200) planes. In acidic solution, the overpotential of such a foil (10 mA cm(−2)) was found to be 136 mV lower than that of a similar rolled copper foil. The calculation results show that hollow sites formed on the (200) plane have the highest hydrogen adsorption energy and are active centers for hydrogen evolution. Thus, this work clarifies the catalytic activity of specific sites on the copper surface and demonstrates the critical role of surface engineering in designing catalytic properties.