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Hybrid Carbon Nanocomposites Made of Aerospace-Grade Epoxy Showing Synergistic Effects in Electrical Properties and High Processability

In this work, we investigate the processability and the volumetric electrical properties of nanocomposites made of aerospace-grade RTM6, loaded with different carbon nanoparticles. Nanocomposites with graphene nanoplatelets (GNP), single-walled carbon nanotubes (SWCNT) and hybrid GNP/SWCNT in the ra...

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Autores principales: Zaccardi, Federica, Toto, Elisa, Marra, Fabrizio, Santonicola, Maria Gabriella, Laurenzi, Susanna
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10007066/
https://www.ncbi.nlm.nih.gov/pubmed/36904403
http://dx.doi.org/10.3390/polym15051163
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author Zaccardi, Federica
Toto, Elisa
Marra, Fabrizio
Santonicola, Maria Gabriella
Laurenzi, Susanna
author_facet Zaccardi, Federica
Toto, Elisa
Marra, Fabrizio
Santonicola, Maria Gabriella
Laurenzi, Susanna
author_sort Zaccardi, Federica
collection PubMed
description In this work, we investigate the processability and the volumetric electrical properties of nanocomposites made of aerospace-grade RTM6, loaded with different carbon nanoparticles. Nanocomposites with graphene nanoplatelets (GNP), single-walled carbon nanotubes (SWCNT) and hybrid GNP/SWCNT in the ratio 2:8 (GNP(2)SWCNT(8)), 5:5 (GNP(5)SWCNT(5)) and 8:2 (GNP(8)SWCNT(2)) were manufactured and analyzed. The hybrid nanofillers are observed to have synergistic properties as epoxy/hybrid mixtures showed better processability than epoxy/SWCNT, while maintaining high values of electrical conductivity. On the other hand, epoxy/SWCNT nanocomposites present the highest electrical conductivities with the formation of a percolating conductive network at lower filler content, but very large viscosity values and filler dispersion issues, which significantly affect the final quality of the samples. Hybrid nanofiller allows us to overcome the manufacturing issues typically associated with the use of SWCNTs. The combination of low viscosity and high electrical conductivity makes the hybrid nanofiller a good candidate for the fabrication of aerospace-grade nanocomposites with multifunctional properties.
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spelling pubmed-100070662023-03-12 Hybrid Carbon Nanocomposites Made of Aerospace-Grade Epoxy Showing Synergistic Effects in Electrical Properties and High Processability Zaccardi, Federica Toto, Elisa Marra, Fabrizio Santonicola, Maria Gabriella Laurenzi, Susanna Polymers (Basel) Article In this work, we investigate the processability and the volumetric electrical properties of nanocomposites made of aerospace-grade RTM6, loaded with different carbon nanoparticles. Nanocomposites with graphene nanoplatelets (GNP), single-walled carbon nanotubes (SWCNT) and hybrid GNP/SWCNT in the ratio 2:8 (GNP(2)SWCNT(8)), 5:5 (GNP(5)SWCNT(5)) and 8:2 (GNP(8)SWCNT(2)) were manufactured and analyzed. The hybrid nanofillers are observed to have synergistic properties as epoxy/hybrid mixtures showed better processability than epoxy/SWCNT, while maintaining high values of electrical conductivity. On the other hand, epoxy/SWCNT nanocomposites present the highest electrical conductivities with the formation of a percolating conductive network at lower filler content, but very large viscosity values and filler dispersion issues, which significantly affect the final quality of the samples. Hybrid nanofiller allows us to overcome the manufacturing issues typically associated with the use of SWCNTs. The combination of low viscosity and high electrical conductivity makes the hybrid nanofiller a good candidate for the fabrication of aerospace-grade nanocomposites with multifunctional properties. MDPI 2023-02-25 /pmc/articles/PMC10007066/ /pubmed/36904403 http://dx.doi.org/10.3390/polym15051163 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Zaccardi, Federica
Toto, Elisa
Marra, Fabrizio
Santonicola, Maria Gabriella
Laurenzi, Susanna
Hybrid Carbon Nanocomposites Made of Aerospace-Grade Epoxy Showing Synergistic Effects in Electrical Properties and High Processability
title Hybrid Carbon Nanocomposites Made of Aerospace-Grade Epoxy Showing Synergistic Effects in Electrical Properties and High Processability
title_full Hybrid Carbon Nanocomposites Made of Aerospace-Grade Epoxy Showing Synergistic Effects in Electrical Properties and High Processability
title_fullStr Hybrid Carbon Nanocomposites Made of Aerospace-Grade Epoxy Showing Synergistic Effects in Electrical Properties and High Processability
title_full_unstemmed Hybrid Carbon Nanocomposites Made of Aerospace-Grade Epoxy Showing Synergistic Effects in Electrical Properties and High Processability
title_short Hybrid Carbon Nanocomposites Made of Aerospace-Grade Epoxy Showing Synergistic Effects in Electrical Properties and High Processability
title_sort hybrid carbon nanocomposites made of aerospace-grade epoxy showing synergistic effects in electrical properties and high processability
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10007066/
https://www.ncbi.nlm.nih.gov/pubmed/36904403
http://dx.doi.org/10.3390/polym15051163
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