Solid State Polymerization of Biodegradable Poly(butylene sebacate-co-terephthalate): A Rapid, Facile Method for Property Enhancement

Poly(butylene sebacate-co-terephthalate) (PBSeT) has generated attention as a promising biopolymer for preparing bioplastics. However, there are limited studies on the synthesis of PBSeT, impeding its commercialization. Herein, with a view to addressing this challenge, biodegradable PBSeT was modified using solid state polymerization (SSP) with various ranges of time and temperature. The SSP used three different temperatures below the melting temperature of PBSeT. The polymerization degree of SSP was investigated using Fourier-transform infrared spectroscopy. The changes in the rheological properties of PBSeT after SSP were investigated using a rheometer and an Ubbelodhe viscometer. Differential scanning calorimetry and X-ray diffraction showed that the crystallinity of PBSeT was higher after SSP. The investigation revealed that after SSP for 40 min at 90 °C, PBSeT exhibited higher intrinsic viscosity (increased from 0.47 to 0.53 dL/g), crystallinity, and complex viscosity than PBSeT polymerized at other temperatures. However, a high SSP processing time resulted in a decrease in these values. In this experiment, SSP was most effectively performed in the temperature range closest to the melting temperature of PBSeT. This indicates that SSP could be a facile and rapid method for improving the crystallinity and thermal stability of synthesized PBSeT.