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Investigation of the Mechanical Properties of Quick-Strength Geopolymer Material Considering Preheated-to-Room Temperature Ratio of Sand, Na(2)SiO(3)-to-NaOH Ratio, and Fly Ash-to-GGBS Ratio

Geopolymer concrete is a useful alternative construction material for bridge deck systems, as it is characterized by a low carbon footprint, rapid setting, quick strength development, low cost, freeze-thaw resistance, low shrinkage, and sulphate and corrosion resistance. Heat curing enhances the mec...

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Autores principales: Bhina, Mohammad Rizwan, Liu, Kuang-Yen, Hu, John-Eric Hsin-Yu, Tsai, Chih-Ta
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10007510/
https://www.ncbi.nlm.nih.gov/pubmed/36904325
http://dx.doi.org/10.3390/polym15051084
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author Bhina, Mohammad Rizwan
Liu, Kuang-Yen
Hu, John-Eric Hsin-Yu
Tsai, Chih-Ta
author_facet Bhina, Mohammad Rizwan
Liu, Kuang-Yen
Hu, John-Eric Hsin-Yu
Tsai, Chih-Ta
author_sort Bhina, Mohammad Rizwan
collection PubMed
description Geopolymer concrete is a useful alternative construction material for bridge deck systems, as it is characterized by a low carbon footprint, rapid setting, quick strength development, low cost, freeze-thaw resistance, low shrinkage, and sulphate and corrosion resistance. Heat curing enhances the mechanical properties of geopolymer materials (GPM), but it is not suitable for large structures, as it affects construction activities and increases energy consumption. Therefore, this study investigated the effect of preheated sand at varying temperatures on GPM compressive strength (Cs), the influence of Na(2)SiO(3) (sodium silicate)-to-NaOH (sodium hydroxide—10 molar concentration), and fly ash-to-granulated blast furnace slag (GGBS) ratios on the workability, setting time, and mechanical strength properties of high-performance GPM. The results indicate that a mix design with preheated sand improved the Cs of the GPM compared to sand at room temperature (25 ± 2 °C). This was caused by the heat energy increasing the kinetics of the polymerization reaction under similar curing conditions and with a similar curing period and fly ash-to-GGBS quantity. Additionally, 110 °C was shown to be the optimal preheated sand temperature in terms of enhancing the Cs of the GPM. A Cs of 52.56 MPa was achieved after three hours of hot oven curing at a constant temperature of 50 °C. GGBS in the geopolymer paste increased the mechanical and microstructure properties of the GPM as a result of different formations of crystalline calcium silicate (C-S-H) gel. The synthesis of C-S-H and amorphous gel in the Na(2)SiO(3) (SS) and NaOH (SH) solution increased the Cs of the GPM. We conclude that a Na(2)SiO(3)-to-NaOH ratio (SS-to-SH) of 5% was optimal in terms of enhancing the Cs of the GPM for sand preheated at 110 °C. Additionally, as the quantity of ground GGBS in the geopolymer paste increased, the thermal resistance of the GPM was significantly reduced.
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spelling pubmed-100075102023-03-12 Investigation of the Mechanical Properties of Quick-Strength Geopolymer Material Considering Preheated-to-Room Temperature Ratio of Sand, Na(2)SiO(3)-to-NaOH Ratio, and Fly Ash-to-GGBS Ratio Bhina, Mohammad Rizwan Liu, Kuang-Yen Hu, John-Eric Hsin-Yu Tsai, Chih-Ta Polymers (Basel) Article Geopolymer concrete is a useful alternative construction material for bridge deck systems, as it is characterized by a low carbon footprint, rapid setting, quick strength development, low cost, freeze-thaw resistance, low shrinkage, and sulphate and corrosion resistance. Heat curing enhances the mechanical properties of geopolymer materials (GPM), but it is not suitable for large structures, as it affects construction activities and increases energy consumption. Therefore, this study investigated the effect of preheated sand at varying temperatures on GPM compressive strength (Cs), the influence of Na(2)SiO(3) (sodium silicate)-to-NaOH (sodium hydroxide—10 molar concentration), and fly ash-to-granulated blast furnace slag (GGBS) ratios on the workability, setting time, and mechanical strength properties of high-performance GPM. The results indicate that a mix design with preheated sand improved the Cs of the GPM compared to sand at room temperature (25 ± 2 °C). This was caused by the heat energy increasing the kinetics of the polymerization reaction under similar curing conditions and with a similar curing period and fly ash-to-GGBS quantity. Additionally, 110 °C was shown to be the optimal preheated sand temperature in terms of enhancing the Cs of the GPM. A Cs of 52.56 MPa was achieved after three hours of hot oven curing at a constant temperature of 50 °C. GGBS in the geopolymer paste increased the mechanical and microstructure properties of the GPM as a result of different formations of crystalline calcium silicate (C-S-H) gel. The synthesis of C-S-H and amorphous gel in the Na(2)SiO(3) (SS) and NaOH (SH) solution increased the Cs of the GPM. We conclude that a Na(2)SiO(3)-to-NaOH ratio (SS-to-SH) of 5% was optimal in terms of enhancing the Cs of the GPM for sand preheated at 110 °C. Additionally, as the quantity of ground GGBS in the geopolymer paste increased, the thermal resistance of the GPM was significantly reduced. MDPI 2023-02-21 /pmc/articles/PMC10007510/ /pubmed/36904325 http://dx.doi.org/10.3390/polym15051084 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Bhina, Mohammad Rizwan
Liu, Kuang-Yen
Hu, John-Eric Hsin-Yu
Tsai, Chih-Ta
Investigation of the Mechanical Properties of Quick-Strength Geopolymer Material Considering Preheated-to-Room Temperature Ratio of Sand, Na(2)SiO(3)-to-NaOH Ratio, and Fly Ash-to-GGBS Ratio
title Investigation of the Mechanical Properties of Quick-Strength Geopolymer Material Considering Preheated-to-Room Temperature Ratio of Sand, Na(2)SiO(3)-to-NaOH Ratio, and Fly Ash-to-GGBS Ratio
title_full Investigation of the Mechanical Properties of Quick-Strength Geopolymer Material Considering Preheated-to-Room Temperature Ratio of Sand, Na(2)SiO(3)-to-NaOH Ratio, and Fly Ash-to-GGBS Ratio
title_fullStr Investigation of the Mechanical Properties of Quick-Strength Geopolymer Material Considering Preheated-to-Room Temperature Ratio of Sand, Na(2)SiO(3)-to-NaOH Ratio, and Fly Ash-to-GGBS Ratio
title_full_unstemmed Investigation of the Mechanical Properties of Quick-Strength Geopolymer Material Considering Preheated-to-Room Temperature Ratio of Sand, Na(2)SiO(3)-to-NaOH Ratio, and Fly Ash-to-GGBS Ratio
title_short Investigation of the Mechanical Properties of Quick-Strength Geopolymer Material Considering Preheated-to-Room Temperature Ratio of Sand, Na(2)SiO(3)-to-NaOH Ratio, and Fly Ash-to-GGBS Ratio
title_sort investigation of the mechanical properties of quick-strength geopolymer material considering preheated-to-room temperature ratio of sand, na(2)sio(3)-to-naoh ratio, and fly ash-to-ggbs ratio
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10007510/
https://www.ncbi.nlm.nih.gov/pubmed/36904325
http://dx.doi.org/10.3390/polym15051084
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