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Foam coarsening under a steady shear: interplay between bubble rearrangement and film thinning dynamics

Aqueous foams are unstable and age by drainage and coarsening. Today, these effects are well described, as also their impact on foam properties. In that respect, the foam viscoelastic properties evolve in time as a consequence of coarsening which tends to increase the mean bubble size. Here, we inve...

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Autores principales: Saint-Jalmes, Arnaud, Trégouët, Corentin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10015626/
https://www.ncbi.nlm.nih.gov/pubmed/36853265
http://dx.doi.org/10.1039/d2sm01618d
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author Saint-Jalmes, Arnaud
Trégouët, Corentin
author_facet Saint-Jalmes, Arnaud
Trégouët, Corentin
author_sort Saint-Jalmes, Arnaud
collection PubMed
description Aqueous foams are unstable and age by drainage and coarsening. Today, these effects are well described, as also their impact on foam properties. In that respect, the foam viscoelastic properties evolve in time as a consequence of coarsening which tends to increase the mean bubble size. Here, we investigate the reverse coupling, and study if and how the continuous flow of a foam can impact its dynamics of coarsening. We introduce a new protocol where brief oscillatory measurements are inserted during a constant steady shear, allowing us to monitor the relative variation of the bubble size with time (obtained from the one of the elastic modulus G′) as a function of the applied shear rate. It turns out that the coarsening rate is strongly impacted by the applied shear: this rate is continuously reduced above a critical shear rate, which itself decreases with the bubble size. This coarsening-rate reduction is interpreted as the result of out-of-equilibrium and shear-dependent film thicknesses, being higher than at rest. The critical shear rate, above which films are dynamically sustained at higher thickness than at equilibrium, emerges from the competition between the rate of rearrangements and the time required to drain the thick film created during the rearrangement. We thus report here a first experimental proof and measurements of out-of-equilibrium film thicknesses within a sheared foam, and of the impact this has on coarsening.
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spelling pubmed-100156262023-03-16 Foam coarsening under a steady shear: interplay between bubble rearrangement and film thinning dynamics Saint-Jalmes, Arnaud Trégouët, Corentin Soft Matter Chemistry Aqueous foams are unstable and age by drainage and coarsening. Today, these effects are well described, as also their impact on foam properties. In that respect, the foam viscoelastic properties evolve in time as a consequence of coarsening which tends to increase the mean bubble size. Here, we investigate the reverse coupling, and study if and how the continuous flow of a foam can impact its dynamics of coarsening. We introduce a new protocol where brief oscillatory measurements are inserted during a constant steady shear, allowing us to monitor the relative variation of the bubble size with time (obtained from the one of the elastic modulus G′) as a function of the applied shear rate. It turns out that the coarsening rate is strongly impacted by the applied shear: this rate is continuously reduced above a critical shear rate, which itself decreases with the bubble size. This coarsening-rate reduction is interpreted as the result of out-of-equilibrium and shear-dependent film thicknesses, being higher than at rest. The critical shear rate, above which films are dynamically sustained at higher thickness than at equilibrium, emerges from the competition between the rate of rearrangements and the time required to drain the thick film created during the rearrangement. We thus report here a first experimental proof and measurements of out-of-equilibrium film thicknesses within a sheared foam, and of the impact this has on coarsening. The Royal Society of Chemistry 2023-02-17 /pmc/articles/PMC10015626/ /pubmed/36853265 http://dx.doi.org/10.1039/d2sm01618d Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Saint-Jalmes, Arnaud
Trégouët, Corentin
Foam coarsening under a steady shear: interplay between bubble rearrangement and film thinning dynamics
title Foam coarsening under a steady shear: interplay between bubble rearrangement and film thinning dynamics
title_full Foam coarsening under a steady shear: interplay between bubble rearrangement and film thinning dynamics
title_fullStr Foam coarsening under a steady shear: interplay between bubble rearrangement and film thinning dynamics
title_full_unstemmed Foam coarsening under a steady shear: interplay between bubble rearrangement and film thinning dynamics
title_short Foam coarsening under a steady shear: interplay between bubble rearrangement and film thinning dynamics
title_sort foam coarsening under a steady shear: interplay between bubble rearrangement and film thinning dynamics
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10015626/
https://www.ncbi.nlm.nih.gov/pubmed/36853265
http://dx.doi.org/10.1039/d2sm01618d
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