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The Mechanism of Markovnikov-Selective Epoxide Hydrogenolysis Catalyzed by Ruthenium PNN and PNP Pincer Complexes

[Image: see text] The homogeneous catalysis of epoxide hydrogenolysis to give alcohols has recently received significant attention. Catalyst systems have been developed for the selective formation of either the Markovnikov (branched) or anti-Markovnikov (linear) alcohol product. Thus far, the report...

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Detalles Bibliográficos
Autores principales: Head, Marianna C., Joseph, Benjamin T., Keith, Jason M., Chianese, Anthony R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10015984/
https://www.ncbi.nlm.nih.gov/pubmed/36937786
http://dx.doi.org/10.1021/acs.organomet.2c00503