Photochemical formation and reversible base-induced cleavage of a phosphagallene

The reactivity of Cp*Ga (Cp* = C(5)Me(5)) towards phosphanylidenephosphoranes of the type (Ar)TerP(PMe(3)) ((Ar)Ter = (Dip)Ter 2,6-(2,6-iPr(2)C(6)H(3))(2)C(6)H(3)), (Tip)Ter 2,6-(2,4,6-iPr(3)C(6)H(2))(2)C(6)H(3) was investigated. While no thermal reaction was observed (in line with DFT results), irr...

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Detalles Bibliográficos
Autores principales: Taeufer, T., Dankert, F., Michalik, D., Pospech, J., Bresien, J., Hering-Junghans, C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10016425/
https://www.ncbi.nlm.nih.gov/pubmed/36937589
http://dx.doi.org/10.1039/d2sc06292e

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