Stepwise assembly of heterometallic, heteroleptic “triblock Janus-type” metal–organic polyhedra

Increasing the chemical complexity of metal–organic cages (MOCs) or polyhedra (MOPs) demands control over the simultaneous organization of diverse organic linkers and metal ions into discrete caged structures. Herein, we show that a pre-assembled complex of the archetypical cuboctahedral MOP can be...

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Detalles Bibliográficos
Autores principales: von Baeckmann, Cornelia, Ruiz-Relaño, Sara, Imaz, Inhar, Handke, Marcel, Juanhuix, Judith, Gándara, Felipe, Carné-Sanchez, Arnau, Maspoch, Daniel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10019128/
https://www.ncbi.nlm.nih.gov/pubmed/36853262
http://dx.doi.org/10.1039/d2cc06815j
Descripción
Sumario:Increasing the chemical complexity of metal–organic cages (MOCs) or polyhedra (MOPs) demands control over the simultaneous organization of diverse organic linkers and metal ions into discrete caged structures. Herein, we show that a pre-assembled complex of the archetypical cuboctahedral MOP can be used as a template to replicate such caged structure, one having a “triblock Janus-type” configuration that is both heterometallic and heteroleptic.

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