Pd/Xu-Phos-catalyzed asymmetric elimination of fully substituted enol triflates into axially chiral trisubstituted allenes

The β-H elimination, as one of the most important elementary reactions in transition metal chemistry, is a key step in quenching the carbon-palladium bond for the Heck reaction. However, the β-H elimination of the alkenyl palladium species leading to allene is an energetically unfavored process, and...

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Detalles Bibliográficos
Autores principales: Han, Jie, Liu, Siyuan, Wang, Huanan, Wang, Jie, Qian, Hui, Li, Zhiming, Ma, Shengming, Zhang, Junliang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Association for the Advancement of Science 2023
Materias:
Physical and Materials Sciences
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10022902/
https://www.ncbi.nlm.nih.gov/pubmed/36930705
http://dx.doi.org/10.1126/sciadv.adg1002

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10022902/
https://www.ncbi.nlm.nih.gov/pubmed/36930705
http://dx.doi.org/10.1126/sciadv.adg1002

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