Distinct morphology-dependent behaviors for Au/γ-Al(2)O(3) catalysts: enhanced thermal stabilization in CO oxidation reaction

The durability of supported metal catalysts usually suffers from sintering, the metal nanoparticles aggregating into larger sizes and subsequent loss of reactive surface, resulting in catalysts deactivation when heated at elevated temperatures. Herein, we investigate the evolution of Au species on different morphologies of γ-Al(2)O(3) and surprisingly found vastly different behavior for the dispersion of surface Au nanoparticles. A nanorod-shaped γ-Al(2)O(3) is prepared by the hydrothermal method resulting in an extraordinary catalyst support that can stabilize Au nanoparticles at annealing temperatures up to 700 °C. In contrast, the Au-supported catalyst prepared using commercial γ-Al(2)O(3) shows a greater degree of inactivation under the same conditions. Remarkably, the unique morphology of such nanorod-shaped γ-Al(2)O(3) is beneficial in preventing Au nanoparticles from sintering. The γ-Al(2)O(3) nanorods are more effective than the commercial γ-Al(2)O(3) at anchoring the Au nanoparticles. The results of X-ray photoelectron spectroscopy (XPS), in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and H(2)-TPR, reveal the interfacial interactions between Au nanoparticles and γ-Al(2)O(3) nanorods, yielding a sinter-stability of the obtained Au/γ-Al(2)O(3) nanorods catalyst. This synthetic strategy is simple and amenable to the large-scale manufacture of thermally stable γ-Al(2)O(3) for industrial applications. Here, we investigate the morphology-dependent behavior of Au nanoparticles dispersed on different morphologies of γ-Al(2)O(3). The result of X-ray photoelectron spectroscopy (XPS), in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and H(2)-TPR, reveal the interfacial interactions between Au nanoparticles and gamma alumina nanorods. Au nanoparticles on γ-Al(2)O(3) nanorods exhibit higher sinter-resistant performance than those on commercial γ-Al(2)O(3).