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Research on the physical properties of LiMn(0.5)Fe(2)O(4) spinel ferrites by the combination of optical, magnetic, and dielectric behaviors

Ferrite compounds have recently attracted significant interest because of their multifunctional properties. This work investigates the optical, magnetic, and dielectric properties of a LiMn(0.5)Fe(2)O(4) ferrite prepared by a solid-state reaction. Raman spectroscopy analysis substantiated the presen...

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Autores principales: Soudani, Ibtihel, Ben Brahim, Khawla, Oueslati, Abderrazek, Aydi, Abdelhedi, Khirouni, Kamel, Benali, A., Dhahri, E., Valente, M. A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10026823/
https://www.ncbi.nlm.nih.gov/pubmed/36950711
http://dx.doi.org/10.1039/d3ra00985h
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author Soudani, Ibtihel
Ben Brahim, Khawla
Oueslati, Abderrazek
Aydi, Abdelhedi
Khirouni, Kamel
Benali, A.
Dhahri, E.
Valente, M. A.
author_facet Soudani, Ibtihel
Ben Brahim, Khawla
Oueslati, Abderrazek
Aydi, Abdelhedi
Khirouni, Kamel
Benali, A.
Dhahri, E.
Valente, M. A.
author_sort Soudani, Ibtihel
collection PubMed
description Ferrite compounds have recently attracted significant interest because of their multifunctional properties. This work investigates the optical, magnetic, and dielectric properties of a LiMn(0.5)Fe(2)O(4) ferrite prepared by a solid-state reaction. Raman spectroscopy analysis substantiated the presence of the 5 active modes representing the vibration of the oxygen anion at both tetrahedral and octahedral sites. The direct optical band gap was estimated to be 3.51 eV, which indicates the semiconductor behavior of the compound. A theoretical modulation of the hysteresis loop was done to confirm the dominance of the ferromagnetic contribution over the antiferromagnetic one. Furthermore, the dielectric permittivity result indicated a colossal value of the order of 10(3). The dielectric losses are characterized by the Giuntini law to extract the relaxation process, which is hidden by the DC-conductivity process. Our results indicate the potential of LiMn(0.5)Fe(2)O(4) for applications in multifunctional devices.
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spelling pubmed-100268232023-03-21 Research on the physical properties of LiMn(0.5)Fe(2)O(4) spinel ferrites by the combination of optical, magnetic, and dielectric behaviors Soudani, Ibtihel Ben Brahim, Khawla Oueslati, Abderrazek Aydi, Abdelhedi Khirouni, Kamel Benali, A. Dhahri, E. Valente, M. A. RSC Adv Chemistry Ferrite compounds have recently attracted significant interest because of their multifunctional properties. This work investigates the optical, magnetic, and dielectric properties of a LiMn(0.5)Fe(2)O(4) ferrite prepared by a solid-state reaction. Raman spectroscopy analysis substantiated the presence of the 5 active modes representing the vibration of the oxygen anion at both tetrahedral and octahedral sites. The direct optical band gap was estimated to be 3.51 eV, which indicates the semiconductor behavior of the compound. A theoretical modulation of the hysteresis loop was done to confirm the dominance of the ferromagnetic contribution over the antiferromagnetic one. Furthermore, the dielectric permittivity result indicated a colossal value of the order of 10(3). The dielectric losses are characterized by the Giuntini law to extract the relaxation process, which is hidden by the DC-conductivity process. Our results indicate the potential of LiMn(0.5)Fe(2)O(4) for applications in multifunctional devices. The Royal Society of Chemistry 2023-03-20 /pmc/articles/PMC10026823/ /pubmed/36950711 http://dx.doi.org/10.1039/d3ra00985h Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Soudani, Ibtihel
Ben Brahim, Khawla
Oueslati, Abderrazek
Aydi, Abdelhedi
Khirouni, Kamel
Benali, A.
Dhahri, E.
Valente, M. A.
Research on the physical properties of LiMn(0.5)Fe(2)O(4) spinel ferrites by the combination of optical, magnetic, and dielectric behaviors
title Research on the physical properties of LiMn(0.5)Fe(2)O(4) spinel ferrites by the combination of optical, magnetic, and dielectric behaviors
title_full Research on the physical properties of LiMn(0.5)Fe(2)O(4) spinel ferrites by the combination of optical, magnetic, and dielectric behaviors
title_fullStr Research on the physical properties of LiMn(0.5)Fe(2)O(4) spinel ferrites by the combination of optical, magnetic, and dielectric behaviors
title_full_unstemmed Research on the physical properties of LiMn(0.5)Fe(2)O(4) spinel ferrites by the combination of optical, magnetic, and dielectric behaviors
title_short Research on the physical properties of LiMn(0.5)Fe(2)O(4) spinel ferrites by the combination of optical, magnetic, and dielectric behaviors
title_sort research on the physical properties of limn(0.5)fe(2)o(4) spinel ferrites by the combination of optical, magnetic, and dielectric behaviors
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10026823/
https://www.ncbi.nlm.nih.gov/pubmed/36950711
http://dx.doi.org/10.1039/d3ra00985h
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