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Rapid handheld time-resolved circularly polarised luminescence photography camera for life and material sciences

Circularly polarised luminescence (CPL) is gaining a rapidly increasing following and finding new applications in both life and material sciences. Spurred by recent instrumental advancements, the development of CPL active chiral emitters is going through a renaissance, especially the design and synt...

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Autores principales: De Rosa, Davide F., Stachelek, Patrycja, Black, Dominic J., Pal, Robert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10027819/
https://www.ncbi.nlm.nih.gov/pubmed/36941271
http://dx.doi.org/10.1038/s41467-023-37329-8
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author De Rosa, Davide F.
Stachelek, Patrycja
Black, Dominic J.
Pal, Robert
author_facet De Rosa, Davide F.
Stachelek, Patrycja
Black, Dominic J.
Pal, Robert
author_sort De Rosa, Davide F.
collection PubMed
description Circularly polarised luminescence (CPL) is gaining a rapidly increasing following and finding new applications in both life and material sciences. Spurred by recent instrumental advancements, the development of CPL active chiral emitters is going through a renaissance, especially the design and synthesis of CPL active luminescent lanthanide complexes owing to their unique and robust photophysical properties. They possess superior circularly polarised brightness (CPB) and can encode vital chiral molecular fingerprints in their long-lived emission spectrum. However, their application as embedded CPL emitters in intelligent security inks has not yet been fully exploited. This major bottleneck is purely hardware related: there is currently no suitable compact CPL instrumentation available, and handheld CPL photography remains an uncharted territory. Here we present a solution: an all solid-state small footprint CPL camera with no moving parts to facilitate ad hoc time-resolved enantioselective differential chiral contrast (EDCC) based one-shot CPL photography (CPLP).
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spelling pubmed-100278192023-03-22 Rapid handheld time-resolved circularly polarised luminescence photography camera for life and material sciences De Rosa, Davide F. Stachelek, Patrycja Black, Dominic J. Pal, Robert Nat Commun Article Circularly polarised luminescence (CPL) is gaining a rapidly increasing following and finding new applications in both life and material sciences. Spurred by recent instrumental advancements, the development of CPL active chiral emitters is going through a renaissance, especially the design and synthesis of CPL active luminescent lanthanide complexes owing to their unique and robust photophysical properties. They possess superior circularly polarised brightness (CPB) and can encode vital chiral molecular fingerprints in their long-lived emission spectrum. However, their application as embedded CPL emitters in intelligent security inks has not yet been fully exploited. This major bottleneck is purely hardware related: there is currently no suitable compact CPL instrumentation available, and handheld CPL photography remains an uncharted territory. Here we present a solution: an all solid-state small footprint CPL camera with no moving parts to facilitate ad hoc time-resolved enantioselective differential chiral contrast (EDCC) based one-shot CPL photography (CPLP). Nature Publishing Group UK 2023-03-20 /pmc/articles/PMC10027819/ /pubmed/36941271 http://dx.doi.org/10.1038/s41467-023-37329-8 Text en © The Author(s) 2023 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) .
spellingShingle Article
De Rosa, Davide F.
Stachelek, Patrycja
Black, Dominic J.
Pal, Robert
Rapid handheld time-resolved circularly polarised luminescence photography camera for life and material sciences
title Rapid handheld time-resolved circularly polarised luminescence photography camera for life and material sciences
title_full Rapid handheld time-resolved circularly polarised luminescence photography camera for life and material sciences
title_fullStr Rapid handheld time-resolved circularly polarised luminescence photography camera for life and material sciences
title_full_unstemmed Rapid handheld time-resolved circularly polarised luminescence photography camera for life and material sciences
title_short Rapid handheld time-resolved circularly polarised luminescence photography camera for life and material sciences
title_sort rapid handheld time-resolved circularly polarised luminescence photography camera for life and material sciences
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10027819/
https://www.ncbi.nlm.nih.gov/pubmed/36941271
http://dx.doi.org/10.1038/s41467-023-37329-8
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