Cargando…
Rapid handheld time-resolved circularly polarised luminescence photography camera for life and material sciences
Circularly polarised luminescence (CPL) is gaining a rapidly increasing following and finding new applications in both life and material sciences. Spurred by recent instrumental advancements, the development of CPL active chiral emitters is going through a renaissance, especially the design and synt...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2023
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10027819/ https://www.ncbi.nlm.nih.gov/pubmed/36941271 http://dx.doi.org/10.1038/s41467-023-37329-8 |
_version_ | 1784909796999168000 |
---|---|
author | De Rosa, Davide F. Stachelek, Patrycja Black, Dominic J. Pal, Robert |
author_facet | De Rosa, Davide F. Stachelek, Patrycja Black, Dominic J. Pal, Robert |
author_sort | De Rosa, Davide F. |
collection | PubMed |
description | Circularly polarised luminescence (CPL) is gaining a rapidly increasing following and finding new applications in both life and material sciences. Spurred by recent instrumental advancements, the development of CPL active chiral emitters is going through a renaissance, especially the design and synthesis of CPL active luminescent lanthanide complexes owing to their unique and robust photophysical properties. They possess superior circularly polarised brightness (CPB) and can encode vital chiral molecular fingerprints in their long-lived emission spectrum. However, their application as embedded CPL emitters in intelligent security inks has not yet been fully exploited. This major bottleneck is purely hardware related: there is currently no suitable compact CPL instrumentation available, and handheld CPL photography remains an uncharted territory. Here we present a solution: an all solid-state small footprint CPL camera with no moving parts to facilitate ad hoc time-resolved enantioselective differential chiral contrast (EDCC) based one-shot CPL photography (CPLP). |
format | Online Article Text |
id | pubmed-10027819 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | Nature Publishing Group UK |
record_format | MEDLINE/PubMed |
spelling | pubmed-100278192023-03-22 Rapid handheld time-resolved circularly polarised luminescence photography camera for life and material sciences De Rosa, Davide F. Stachelek, Patrycja Black, Dominic J. Pal, Robert Nat Commun Article Circularly polarised luminescence (CPL) is gaining a rapidly increasing following and finding new applications in both life and material sciences. Spurred by recent instrumental advancements, the development of CPL active chiral emitters is going through a renaissance, especially the design and synthesis of CPL active luminescent lanthanide complexes owing to their unique and robust photophysical properties. They possess superior circularly polarised brightness (CPB) and can encode vital chiral molecular fingerprints in their long-lived emission spectrum. However, their application as embedded CPL emitters in intelligent security inks has not yet been fully exploited. This major bottleneck is purely hardware related: there is currently no suitable compact CPL instrumentation available, and handheld CPL photography remains an uncharted territory. Here we present a solution: an all solid-state small footprint CPL camera with no moving parts to facilitate ad hoc time-resolved enantioselective differential chiral contrast (EDCC) based one-shot CPL photography (CPLP). Nature Publishing Group UK 2023-03-20 /pmc/articles/PMC10027819/ /pubmed/36941271 http://dx.doi.org/10.1038/s41467-023-37329-8 Text en © The Author(s) 2023 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) . |
spellingShingle | Article De Rosa, Davide F. Stachelek, Patrycja Black, Dominic J. Pal, Robert Rapid handheld time-resolved circularly polarised luminescence photography camera for life and material sciences |
title | Rapid handheld time-resolved circularly polarised luminescence photography camera for life and material sciences |
title_full | Rapid handheld time-resolved circularly polarised luminescence photography camera for life and material sciences |
title_fullStr | Rapid handheld time-resolved circularly polarised luminescence photography camera for life and material sciences |
title_full_unstemmed | Rapid handheld time-resolved circularly polarised luminescence photography camera for life and material sciences |
title_short | Rapid handheld time-resolved circularly polarised luminescence photography camera for life and material sciences |
title_sort | rapid handheld time-resolved circularly polarised luminescence photography camera for life and material sciences |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10027819/ https://www.ncbi.nlm.nih.gov/pubmed/36941271 http://dx.doi.org/10.1038/s41467-023-37329-8 |
work_keys_str_mv | AT derosadavidef rapidhandheldtimeresolvedcircularlypolarisedluminescencephotographycameraforlifeandmaterialsciences AT stachelekpatrycja rapidhandheldtimeresolvedcircularlypolarisedluminescencephotographycameraforlifeandmaterialsciences AT blackdominicj rapidhandheldtimeresolvedcircularlypolarisedluminescencephotographycameraforlifeandmaterialsciences AT palrobert rapidhandheldtimeresolvedcircularlypolarisedluminescencephotographycameraforlifeandmaterialsciences |