Base-Induced Sulfoxide-Sulfenate Rearrangement of 2-Sulfinyl Dienes for the Regio- and Stereoselective Synthesis of Enantioenriched Dienyl Diols

[Image: see text] The base-induced [2,3]-sigmatropic rearrangement of a series of enantiopure 2-sulfinyl dienes has been examined and optimized using a combination of NaH and (i)PrOH. The reaction takes place by allylic deprotonation of the 2-sulfinyl diene to give a bis-allylic sulfoxide anion inte...

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Detalles Bibliográficos
Autores principales: Velado, Marina, Martinović, Manuel, Alonso, Inés, Tortosa, Mariola, Fernández de la Pradilla, Roberto, Viso, Alma
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10028699/
https://www.ncbi.nlm.nih.gov/pubmed/36868575
http://dx.doi.org/10.1021/acs.joc.2c02931

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10028699/
https://www.ncbi.nlm.nih.gov/pubmed/36868575
http://dx.doi.org/10.1021/acs.joc.2c02931

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