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Polarized Au(i)/Rh(i) bimetallic pairs cooperatively trigger ligand non-innocence and bond activation

The combination of molecular metallic fragments of contrasting Lewis character offers many possibilities for cooperative bond activation and for the disclosure of unusual reactivity. Here we provide a systematic investigation on the partnership of Lewis basic Rh(i) compounds of type [(η(5)-L)Rh(PR(3...

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Detalles Bibliográficos
Autores principales: Alférez, Macarena G., Moreno, Juan J., Maya, Celia, Campos, Jesús
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10029337/
https://www.ncbi.nlm.nih.gov/pubmed/36866716
http://dx.doi.org/10.1039/d3dt00410d