Bringing Selectivity in H/D Exchange Reactions Catalyzed by Metal Nanoparticles through Modulation of the Metal and the Ligand Shell

[Image: see text] Ru and Rh nanoparticles catalyze the selective H/D exchange in phosphines using D(2) as the deuterium source. The position of the deuterium incorporation is determined by the structure of the P-based substrates, while activity depends on the nature of the metal, the properties of t...

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Detalles Bibliográficos
Autores principales: Martinez-Espinar, Francisco, Salom-Català, Antoni, Bresó-Femenia, Emma, Claver, Carmen, Baletto, Francesca, Ricart, Josep M., Chaudret, Bruno, Carbó, Jorge J., Godard, Cyril, Castillon, Sergio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10031563/
https://www.ncbi.nlm.nih.gov/pubmed/36893373
http://dx.doi.org/10.1021/acs.inorgchem.2c04442

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