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Novel TiO(2)/GO/M-MMT nano-heterostructured composites exhibiting high photocatalytic activity

This study proposed a technique to enhance the photocatalytic properties of TiO(2) using graphene oxide (GO) and modified Montmorillonite (M-MMT). TiO(2)/GO/M-MMT nano-heterostructured composites were prepared via hydrothermal and co-precipitation. The photocatalytic performance was evaluated by inv...

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Detalles Bibliográficos
Autores principales: Li, W., He, Y., Bao, W. B., Bao, H. L., Li, D. Y., Zhang, C. L., Wang, M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10033540/
https://www.ncbi.nlm.nih.gov/pubmed/36970399
http://dx.doi.org/10.3389/fchem.2023.1113186
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author Li, W.
He, Y.
Bao, W. B.
Bao, H. L.
Li, D. Y.
Zhang, C. L.
Wang, M.
author_facet Li, W.
He, Y.
Bao, W. B.
Bao, H. L.
Li, D. Y.
Zhang, C. L.
Wang, M.
author_sort Li, W.
collection PubMed
description This study proposed a technique to enhance the photocatalytic properties of TiO(2) using graphene oxide (GO) and modified Montmorillonite (M-MMT). TiO(2)/GO/M-MMT nano-heterostructured composites were prepared via hydrothermal and co-precipitation. The photocatalytic performance was evaluated by investigating the photodegradation rate and absorption behavior of methyl orange (MO) under visible light irradiation. The results showed that TiO(2)/GO/M-MMT heterojunction exhibited excellent photocatalytic degradation performance, as the degradation rate of MO was observed to be 99.3% within 150 min. The density of adsorbed MO decreased by 62.1% after 210 min of dark adsorption using the TiO(2)/GO/M-MMT composite, which was significantly higher than that achieved using M-MMT, GO/M-MMT, and TiO(2)/M-MMT. The nano-heterostructure increased the effective interface between TiO(2), GO, and MMT, which increased the charge transfer ability and prolonged the electron-hole separation time. Therefore, the results of this study can be used to design novel photocatalysts to eradicate environmental pollutants.
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spelling pubmed-100335402023-03-24 Novel TiO(2)/GO/M-MMT nano-heterostructured composites exhibiting high photocatalytic activity Li, W. He, Y. Bao, W. B. Bao, H. L. Li, D. Y. Zhang, C. L. Wang, M. Front Chem Chemistry This study proposed a technique to enhance the photocatalytic properties of TiO(2) using graphene oxide (GO) and modified Montmorillonite (M-MMT). TiO(2)/GO/M-MMT nano-heterostructured composites were prepared via hydrothermal and co-precipitation. The photocatalytic performance was evaluated by investigating the photodegradation rate and absorption behavior of methyl orange (MO) under visible light irradiation. The results showed that TiO(2)/GO/M-MMT heterojunction exhibited excellent photocatalytic degradation performance, as the degradation rate of MO was observed to be 99.3% within 150 min. The density of adsorbed MO decreased by 62.1% after 210 min of dark adsorption using the TiO(2)/GO/M-MMT composite, which was significantly higher than that achieved using M-MMT, GO/M-MMT, and TiO(2)/M-MMT. The nano-heterostructure increased the effective interface between TiO(2), GO, and MMT, which increased the charge transfer ability and prolonged the electron-hole separation time. Therefore, the results of this study can be used to design novel photocatalysts to eradicate environmental pollutants. Frontiers Media S.A. 2023-03-09 /pmc/articles/PMC10033540/ /pubmed/36970399 http://dx.doi.org/10.3389/fchem.2023.1113186 Text en Copyright © 2023 Li, He, Bao, Bao, Li, Zhang and Wang. https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
spellingShingle Chemistry
Li, W.
He, Y.
Bao, W. B.
Bao, H. L.
Li, D. Y.
Zhang, C. L.
Wang, M.
Novel TiO(2)/GO/M-MMT nano-heterostructured composites exhibiting high photocatalytic activity
title Novel TiO(2)/GO/M-MMT nano-heterostructured composites exhibiting high photocatalytic activity
title_full Novel TiO(2)/GO/M-MMT nano-heterostructured composites exhibiting high photocatalytic activity
title_fullStr Novel TiO(2)/GO/M-MMT nano-heterostructured composites exhibiting high photocatalytic activity
title_full_unstemmed Novel TiO(2)/GO/M-MMT nano-heterostructured composites exhibiting high photocatalytic activity
title_short Novel TiO(2)/GO/M-MMT nano-heterostructured composites exhibiting high photocatalytic activity
title_sort novel tio(2)/go/m-mmt nano-heterostructured composites exhibiting high photocatalytic activity
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10033540/
https://www.ncbi.nlm.nih.gov/pubmed/36970399
http://dx.doi.org/10.3389/fchem.2023.1113186
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