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Wavelength dependent mechanism of phenolate photooxidation in aqueous solution

Phenolate photooxidation is integral to a range of biological processes, yet the mechanism of electron ejection has been disputed. Here, we combine femtosecond transient absorption spectroscopy, liquid-microjet photoelectron spectroscopy and high-level quantum chemistry calculations to investigate t...

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Detalles Bibliográficos
Autores principales: Robertson, Kate, Fortune, William G., Davies, Julia A., Boichenko, Anton N., Scholz, Michael S., Tau, Omri, Bochenkova, Anastasia V., Fielding, Helen H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10034221/
https://www.ncbi.nlm.nih.gov/pubmed/36970081
http://dx.doi.org/10.1039/d3sc00016h