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Intramolecular crankshaft-type rearrangement in a photoisomerised glycoconjugate

High-resolution NMR spectroscopy revealed that a novel glycoconjugate, consisting of two β-glucopyranoses attached to a quinazolinone-like structure, exhibited photoisomerization around the –N–N[double bond, length as m-dash] and [double bond, length as m-dash]CH–C– bonds of the –N–N[double bond, le...

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Detalles Bibliográficos
Autores principales: Hricovíni, Michal, Asher, James R., Hricovíni, Miloš
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10034262/
https://www.ncbi.nlm.nih.gov/pubmed/36968057
http://dx.doi.org/10.1039/d3ra01678a