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Research progress of catalysts for aldol condensation of biomass based compounds

Research progress of catalysts of the aldol condensation reaction of biomass based compounds is summarized for the synthesis of liquid fuel precursors and chemicals. In summary, an acidic catalyst, alkaline catalyst, acid–base amphoteric catalyst, ionic liquid and other catalysts can catalyze the al...

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Detalles Bibliográficos
Autores principales: Zhang, Xing, Li, YanQing, Qian, Chi, An, Ling, Wang, Wei, Li, XiuFeng, Shao, XianZhao, Li, Zhizhou
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10034479/
https://www.ncbi.nlm.nih.gov/pubmed/36968059
http://dx.doi.org/10.1039/d3ra00906h
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author Zhang, Xing
Li, YanQing
Qian, Chi
An, Ling
Wang, Wei
Li, XiuFeng
Shao, XianZhao
Li, Zhizhou
author_facet Zhang, Xing
Li, YanQing
Qian, Chi
An, Ling
Wang, Wei
Li, XiuFeng
Shao, XianZhao
Li, Zhizhou
author_sort Zhang, Xing
collection PubMed
description Research progress of catalysts of the aldol condensation reaction of biomass based compounds is summarized for the synthesis of liquid fuel precursors and chemicals. In summary, an acidic catalyst, alkaline catalyst, acid–base amphoteric catalyst, ionic liquid and other catalysts can catalyze the aldol condensation reaction. The aldol condensation reaction catalyzed by an acid catalyst has the problems of low conversion and low yield. The basic catalyst catalyzes the aldol condensation reaction with high conversion and yield, but the existence of liquid alkali is difficult to separate from the product. The reaction temperature needed for oxide and hydrotalcite alkali is relatively high. The basic resin has good catalytic activity and at a low reaction temperature, and is easy to separate from the target product. Acid–base amphoteric catalysts have received extensive attention from researchers for their excellent activity and selectivity. Ionic liquid is a new type of material, which can also be used for the aldol condensation reaction. In the future application of aldol condensation, the development of strong alkaline resin is a good research direction.
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spelling pubmed-100344792023-03-24 Research progress of catalysts for aldol condensation of biomass based compounds Zhang, Xing Li, YanQing Qian, Chi An, Ling Wang, Wei Li, XiuFeng Shao, XianZhao Li, Zhizhou RSC Adv Chemistry Research progress of catalysts of the aldol condensation reaction of biomass based compounds is summarized for the synthesis of liquid fuel precursors and chemicals. In summary, an acidic catalyst, alkaline catalyst, acid–base amphoteric catalyst, ionic liquid and other catalysts can catalyze the aldol condensation reaction. The aldol condensation reaction catalyzed by an acid catalyst has the problems of low conversion and low yield. The basic catalyst catalyzes the aldol condensation reaction with high conversion and yield, but the existence of liquid alkali is difficult to separate from the product. The reaction temperature needed for oxide and hydrotalcite alkali is relatively high. The basic resin has good catalytic activity and at a low reaction temperature, and is easy to separate from the target product. Acid–base amphoteric catalysts have received extensive attention from researchers for their excellent activity and selectivity. Ionic liquid is a new type of material, which can also be used for the aldol condensation reaction. In the future application of aldol condensation, the development of strong alkaline resin is a good research direction. The Royal Society of Chemistry 2023-03-23 /pmc/articles/PMC10034479/ /pubmed/36968059 http://dx.doi.org/10.1039/d3ra00906h Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Zhang, Xing
Li, YanQing
Qian, Chi
An, Ling
Wang, Wei
Li, XiuFeng
Shao, XianZhao
Li, Zhizhou
Research progress of catalysts for aldol condensation of biomass based compounds
title Research progress of catalysts for aldol condensation of biomass based compounds
title_full Research progress of catalysts for aldol condensation of biomass based compounds
title_fullStr Research progress of catalysts for aldol condensation of biomass based compounds
title_full_unstemmed Research progress of catalysts for aldol condensation of biomass based compounds
title_short Research progress of catalysts for aldol condensation of biomass based compounds
title_sort research progress of catalysts for aldol condensation of biomass based compounds
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10034479/
https://www.ncbi.nlm.nih.gov/pubmed/36968059
http://dx.doi.org/10.1039/d3ra00906h
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