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Adsorptive Desulfurization of Condensate Contains Aromatic Compounds Using a Commercial Molecular Sieve

[Image: see text] This study is undertaken to evaluate the potential of a commercial molecular sieve to remove diverse sulfur compounds from condensate with high aromatic on an industrial scale. For the first part of this study, the adsorbent is characterized in detail using inductively coupled plas...

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Detalles Bibliográficos
Autores principales: Behbahani Nezhad, Amir, Bastan, Farzad, Panjehshahin, Ahmad, Zamani, Mahdi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10034830/
https://www.ncbi.nlm.nih.gov/pubmed/36969445
http://dx.doi.org/10.1021/acsomega.2c08051
Descripción
Sumario:[Image: see text] This study is undertaken to evaluate the potential of a commercial molecular sieve to remove diverse sulfur compounds from condensate with high aromatic on an industrial scale. For the first part of this study, the adsorbent is characterized in detail using inductively coupled plasma optical emission spectroscopy, X-ray diffraction, field-emission scanning electron microscopy, and Brunauer–Emmett–Teller analysis. For the second part, dynamic breakthrough experiments on an industrial scale are performed to assess the dynamic adsorption performance of a commercial molecular sieve. Dynamic experiments show that the adsorbent effectively removes the sulfur compound from condensate that has approximately 900 ppmw S. In more detail, this commercial molecular sieve selectively desulfurizes condensate to about 12 ppmw S, and this is achieved when the concentration of non-sulfur aromatic is greater than 15 times higher than the total sulfur. As regeneration is a crucial part of the continuous adsorption–regeneration cycling process, the final part of this study is focused on finding a desorption method to avoid a sulfur concentration peak in tail gas.