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Adsorptive Desulfurization of Condensate Contains Aromatic Compounds Using a Commercial Molecular Sieve
[Image: see text] This study is undertaken to evaluate the potential of a commercial molecular sieve to remove diverse sulfur compounds from condensate with high aromatic on an industrial scale. For the first part of this study, the adsorbent is characterized in detail using inductively coupled plas...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10034830/ https://www.ncbi.nlm.nih.gov/pubmed/36969445 http://dx.doi.org/10.1021/acsomega.2c08051 |
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author | Behbahani Nezhad, Amir Bastan, Farzad Panjehshahin, Ahmad Zamani, Mahdi |
author_facet | Behbahani Nezhad, Amir Bastan, Farzad Panjehshahin, Ahmad Zamani, Mahdi |
author_sort | Behbahani Nezhad, Amir |
collection | PubMed |
description | [Image: see text] This study is undertaken to evaluate the potential of a commercial molecular sieve to remove diverse sulfur compounds from condensate with high aromatic on an industrial scale. For the first part of this study, the adsorbent is characterized in detail using inductively coupled plasma optical emission spectroscopy, X-ray diffraction, field-emission scanning electron microscopy, and Brunauer–Emmett–Teller analysis. For the second part, dynamic breakthrough experiments on an industrial scale are performed to assess the dynamic adsorption performance of a commercial molecular sieve. Dynamic experiments show that the adsorbent effectively removes the sulfur compound from condensate that has approximately 900 ppmw S. In more detail, this commercial molecular sieve selectively desulfurizes condensate to about 12 ppmw S, and this is achieved when the concentration of non-sulfur aromatic is greater than 15 times higher than the total sulfur. As regeneration is a crucial part of the continuous adsorption–regeneration cycling process, the final part of this study is focused on finding a desorption method to avoid a sulfur concentration peak in tail gas. |
format | Online Article Text |
id | pubmed-10034830 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-100348302023-03-24 Adsorptive Desulfurization of Condensate Contains Aromatic Compounds Using a Commercial Molecular Sieve Behbahani Nezhad, Amir Bastan, Farzad Panjehshahin, Ahmad Zamani, Mahdi ACS Omega [Image: see text] This study is undertaken to evaluate the potential of a commercial molecular sieve to remove diverse sulfur compounds from condensate with high aromatic on an industrial scale. For the first part of this study, the adsorbent is characterized in detail using inductively coupled plasma optical emission spectroscopy, X-ray diffraction, field-emission scanning electron microscopy, and Brunauer–Emmett–Teller analysis. For the second part, dynamic breakthrough experiments on an industrial scale are performed to assess the dynamic adsorption performance of a commercial molecular sieve. Dynamic experiments show that the adsorbent effectively removes the sulfur compound from condensate that has approximately 900 ppmw S. In more detail, this commercial molecular sieve selectively desulfurizes condensate to about 12 ppmw S, and this is achieved when the concentration of non-sulfur aromatic is greater than 15 times higher than the total sulfur. As regeneration is a crucial part of the continuous adsorption–regeneration cycling process, the final part of this study is focused on finding a desorption method to avoid a sulfur concentration peak in tail gas. American Chemical Society 2023-03-07 /pmc/articles/PMC10034830/ /pubmed/36969445 http://dx.doi.org/10.1021/acsomega.2c08051 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/). |
spellingShingle | Behbahani Nezhad, Amir Bastan, Farzad Panjehshahin, Ahmad Zamani, Mahdi Adsorptive Desulfurization of Condensate Contains Aromatic Compounds Using a Commercial Molecular Sieve |
title | Adsorptive Desulfurization
of Condensate Contains
Aromatic Compounds Using a Commercial Molecular Sieve |
title_full | Adsorptive Desulfurization
of Condensate Contains
Aromatic Compounds Using a Commercial Molecular Sieve |
title_fullStr | Adsorptive Desulfurization
of Condensate Contains
Aromatic Compounds Using a Commercial Molecular Sieve |
title_full_unstemmed | Adsorptive Desulfurization
of Condensate Contains
Aromatic Compounds Using a Commercial Molecular Sieve |
title_short | Adsorptive Desulfurization
of Condensate Contains
Aromatic Compounds Using a Commercial Molecular Sieve |
title_sort | adsorptive desulfurization
of condensate contains
aromatic compounds using a commercial molecular sieve |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10034830/ https://www.ncbi.nlm.nih.gov/pubmed/36969445 http://dx.doi.org/10.1021/acsomega.2c08051 |
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