Impact of Individual Cell Parameter Difference on the Performance of Series–Parallel Battery Packs

[Image: see text] Lithium-ion power batteries are used in groups of series–parallel configurations. There are Ohmic resistance discrepancies, capacity disparities, and polarization differences between individual cells during discharge, preventing a single cell from reaching the lower limit of the terminal voltage simultaneously, resulting in low capacity and energy utilization. The effect of the parameter difference (difference in parameters) of individual cells on the performance of the series–parallel battery pack is simulated and analyzed by grouping cells with different parameters. The findings reveal that when cells are connected in series, the capacity difference is a significant factor impacting the battery pack’s energy index, and the capacity difference and Ohmic resistance difference are significant variables affecting the battery pack’s power index. When cells are connected in parallel, the difference in Ohmic internal resistance between them causes branch current imbalance, low energy utilization in some individual cells, and a sharp expansion of unbalanced current at the end of discharge, which is prone to overdischarge and shortens battery life. Interestingly, we found that when there is an aging cell in a series–parallel battery pack, the terminal voltage of the single battery module containing the aging single cell will decrease sharply at the end of discharge. Evaluating the change rate of battery module terminal voltage at the end of discharge can be used as a method to evaluate the aging degree of the battery module. The research results provide a reference for connecting batteries to battery packs, particularly the screening of retired power battery packs and the way to reconnect into battery packs.