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Synthesis and Surface Properties of Piperidinium-Based Herbicidal Ionic Liquids as a Potential Tool for Weed Control
[Image: see text] A series of piperidinium-based herbicidal ionic liquids (HILs) were synthesized and investigated. The designed HILs, obtained with high yields, consisted of cation 1-alkyl-1-methylpiperidinium with surface activity and a commercially available herbicidal anion: (3,6-dichloro-2-meth...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10037321/ https://www.ncbi.nlm.nih.gov/pubmed/36877199 http://dx.doi.org/10.1021/acs.jafc.3c00356 |
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author | Wojcieszak, Marta Syguda, Anna Lewandowska, Aneta Marcinkowska, Agnieszka Siwińska-Ciesielczyk, Katarzyna Wilkowska, Michalina Kozak, Maciej Materna, Katarzyna |
author_facet | Wojcieszak, Marta Syguda, Anna Lewandowska, Aneta Marcinkowska, Agnieszka Siwińska-Ciesielczyk, Katarzyna Wilkowska, Michalina Kozak, Maciej Materna, Katarzyna |
author_sort | Wojcieszak, Marta |
collection | PubMed |
description | [Image: see text] A series of piperidinium-based herbicidal ionic liquids (HILs) were synthesized and investigated. The designed HILs, obtained with high yields, consisted of cation 1-alkyl-1-methylpiperidinium with surface activity and a commercially available herbicidal anion: (3,6-dichloro-2-methoxy)benzoates (dicamba). The above-mentioned compounds were characterized in terms of surface activity and phytotoxicity. Preliminary results were obtained at higher wettability for all HILs when compared to the wettability of commercial Dicash, with HIL having 18 atoms in the carbon chain being the best effectiveness in wetting surfaces (weeds and crop leaves), whereby a drop of HILs with short alkyl chains (C(8)–C(10)) could not slide down a leaf. Our findings present that wettability or mobility of HILs drops varied depending on the plant species. Moreover, in this study, by zeta potential and atomic force microscopy measurements, we provide conclusive evidence to demonstrate that alkyl chain elongation plays a significant role in the evolution of surface properties of HILs. |
format | Online Article Text |
id | pubmed-10037321 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-100373212023-03-25 Synthesis and Surface Properties of Piperidinium-Based Herbicidal Ionic Liquids as a Potential Tool for Weed Control Wojcieszak, Marta Syguda, Anna Lewandowska, Aneta Marcinkowska, Agnieszka Siwińska-Ciesielczyk, Katarzyna Wilkowska, Michalina Kozak, Maciej Materna, Katarzyna J Agric Food Chem [Image: see text] A series of piperidinium-based herbicidal ionic liquids (HILs) were synthesized and investigated. The designed HILs, obtained with high yields, consisted of cation 1-alkyl-1-methylpiperidinium with surface activity and a commercially available herbicidal anion: (3,6-dichloro-2-methoxy)benzoates (dicamba). The above-mentioned compounds were characterized in terms of surface activity and phytotoxicity. Preliminary results were obtained at higher wettability for all HILs when compared to the wettability of commercial Dicash, with HIL having 18 atoms in the carbon chain being the best effectiveness in wetting surfaces (weeds and crop leaves), whereby a drop of HILs with short alkyl chains (C(8)–C(10)) could not slide down a leaf. Our findings present that wettability or mobility of HILs drops varied depending on the plant species. Moreover, in this study, by zeta potential and atomic force microscopy measurements, we provide conclusive evidence to demonstrate that alkyl chain elongation plays a significant role in the evolution of surface properties of HILs. American Chemical Society 2023-03-06 /pmc/articles/PMC10037321/ /pubmed/36877199 http://dx.doi.org/10.1021/acs.jafc.3c00356 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Wojcieszak, Marta Syguda, Anna Lewandowska, Aneta Marcinkowska, Agnieszka Siwińska-Ciesielczyk, Katarzyna Wilkowska, Michalina Kozak, Maciej Materna, Katarzyna Synthesis and Surface Properties of Piperidinium-Based Herbicidal Ionic Liquids as a Potential Tool for Weed Control |
title | Synthesis and Surface
Properties of Piperidinium-Based
Herbicidal Ionic Liquids as a Potential Tool for Weed Control |
title_full | Synthesis and Surface
Properties of Piperidinium-Based
Herbicidal Ionic Liquids as a Potential Tool for Weed Control |
title_fullStr | Synthesis and Surface
Properties of Piperidinium-Based
Herbicidal Ionic Liquids as a Potential Tool for Weed Control |
title_full_unstemmed | Synthesis and Surface
Properties of Piperidinium-Based
Herbicidal Ionic Liquids as a Potential Tool for Weed Control |
title_short | Synthesis and Surface
Properties of Piperidinium-Based
Herbicidal Ionic Liquids as a Potential Tool for Weed Control |
title_sort | synthesis and surface
properties of piperidinium-based
herbicidal ionic liquids as a potential tool for weed control |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10037321/ https://www.ncbi.nlm.nih.gov/pubmed/36877199 http://dx.doi.org/10.1021/acs.jafc.3c00356 |
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