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Modulation of metal species as control point for Ni-catalyzed stereodivergent semihydrogenation of alkynes with water

A base-assisted metal species modulation mechanism enables Ni-catalyzed stereodivergent transfer semihydrogenation of alkynes with water, delivering both olefinic isomers smoothly using cheap and nontoxic catalysts and additives. Different from most precedents, in which E-alkenes derive from the iso...

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Detalles Bibliográficos
Autores principales:	Wu, Yuanqi, Ao, Yuhui, Li, Zhiming, Liu, Chunhui, Zhao, Jinbo, Gao, Wenyu, Li, Xuemeng, Wang, Hui, Liu, Yongsheng, Liu, Yu
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group UK 2023
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10039052/ https://www.ncbi.nlm.nih.gov/pubmed/36964163 http://dx.doi.org/10.1038/s41467-023-37022-w

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