Cargando…

Excess Enthalpies for Binary Mixtures of the Reactive System Acetic Acid + n-Butanol + n-Butyl Acetate + Water: Brief Data Review and Results at 313.15 K and Atmospheric Pressure

The data on molar excess enthalpies, [Formula: see text] , for the binary mixtures acetic acid + n-butanol, acetic acid + n-butyl acetate and n-butanol + n-butyl acetate at 313.15 K and atmospheric pressure were obtained with use of the C80 isothermal mixing calorimeter (Setaram). The correlation of...

Descripción completa

Detalles Bibliográficos
Autores principales: Golikova, Alexandra, Shasherina, Anna, Anufrikov, Yuri, Misikov, Georgii, Toikka, Maria, Zvereva, Irina, Toikka, Alexander
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10048811/
https://www.ncbi.nlm.nih.gov/pubmed/36982213
http://dx.doi.org/10.3390/ijms24065137
Descripción
Sumario:The data on molar excess enthalpies, [Formula: see text] , for the binary mixtures acetic acid + n-butanol, acetic acid + n-butyl acetate and n-butanol + n-butyl acetate at 313.15 K and atmospheric pressure were obtained with use of the C80 isothermal mixing calorimeter (Setaram). The correlation of the data was carried out using the NRTL model and Redlich–Kister equation. A comparative analysis with the literature data on all available binary subsystems of the quaternary system was carried out. Other thermodynamic properties ([Formula: see text] , [Formula: see text] , [Formula: see text] , [Formula: see text] and [Formula: see text]) of the binary systems were estimated using literature data and well-known formulas of classical thermodynamics.