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Excess Enthalpies for Binary Mixtures of the Reactive System Acetic Acid + n-Butanol + n-Butyl Acetate + Water: Brief Data Review and Results at 313.15 K and Atmospheric Pressure
The data on molar excess enthalpies, [Formula: see text] , for the binary mixtures acetic acid + n-butanol, acetic acid + n-butyl acetate and n-butanol + n-butyl acetate at 313.15 K and atmospheric pressure were obtained with use of the C80 isothermal mixing calorimeter (Setaram). The correlation of...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10048811/ https://www.ncbi.nlm.nih.gov/pubmed/36982213 http://dx.doi.org/10.3390/ijms24065137 |
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author | Golikova, Alexandra Shasherina, Anna Anufrikov, Yuri Misikov, Georgii Toikka, Maria Zvereva, Irina Toikka, Alexander |
author_facet | Golikova, Alexandra Shasherina, Anna Anufrikov, Yuri Misikov, Georgii Toikka, Maria Zvereva, Irina Toikka, Alexander |
author_sort | Golikova, Alexandra |
collection | PubMed |
description | The data on molar excess enthalpies, [Formula: see text] , for the binary mixtures acetic acid + n-butanol, acetic acid + n-butyl acetate and n-butanol + n-butyl acetate at 313.15 K and atmospheric pressure were obtained with use of the C80 isothermal mixing calorimeter (Setaram). The correlation of the data was carried out using the NRTL model and Redlich–Kister equation. A comparative analysis with the literature data on all available binary subsystems of the quaternary system was carried out. Other thermodynamic properties ([Formula: see text] , [Formula: see text] , [Formula: see text] , [Formula: see text] and [Formula: see text]) of the binary systems were estimated using literature data and well-known formulas of classical thermodynamics. |
format | Online Article Text |
id | pubmed-10048811 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-100488112023-03-29 Excess Enthalpies for Binary Mixtures of the Reactive System Acetic Acid + n-Butanol + n-Butyl Acetate + Water: Brief Data Review and Results at 313.15 K and Atmospheric Pressure Golikova, Alexandra Shasherina, Anna Anufrikov, Yuri Misikov, Georgii Toikka, Maria Zvereva, Irina Toikka, Alexander Int J Mol Sci Article The data on molar excess enthalpies, [Formula: see text] , for the binary mixtures acetic acid + n-butanol, acetic acid + n-butyl acetate and n-butanol + n-butyl acetate at 313.15 K and atmospheric pressure were obtained with use of the C80 isothermal mixing calorimeter (Setaram). The correlation of the data was carried out using the NRTL model and Redlich–Kister equation. A comparative analysis with the literature data on all available binary subsystems of the quaternary system was carried out. Other thermodynamic properties ([Formula: see text] , [Formula: see text] , [Formula: see text] , [Formula: see text] and [Formula: see text]) of the binary systems were estimated using literature data and well-known formulas of classical thermodynamics. MDPI 2023-03-07 /pmc/articles/PMC10048811/ /pubmed/36982213 http://dx.doi.org/10.3390/ijms24065137 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Golikova, Alexandra Shasherina, Anna Anufrikov, Yuri Misikov, Georgii Toikka, Maria Zvereva, Irina Toikka, Alexander Excess Enthalpies for Binary Mixtures of the Reactive System Acetic Acid + n-Butanol + n-Butyl Acetate + Water: Brief Data Review and Results at 313.15 K and Atmospheric Pressure |
title | Excess Enthalpies for Binary Mixtures of the Reactive System Acetic Acid + n-Butanol + n-Butyl Acetate + Water: Brief Data Review and Results at 313.15 K and Atmospheric Pressure |
title_full | Excess Enthalpies for Binary Mixtures of the Reactive System Acetic Acid + n-Butanol + n-Butyl Acetate + Water: Brief Data Review and Results at 313.15 K and Atmospheric Pressure |
title_fullStr | Excess Enthalpies for Binary Mixtures of the Reactive System Acetic Acid + n-Butanol + n-Butyl Acetate + Water: Brief Data Review and Results at 313.15 K and Atmospheric Pressure |
title_full_unstemmed | Excess Enthalpies for Binary Mixtures of the Reactive System Acetic Acid + n-Butanol + n-Butyl Acetate + Water: Brief Data Review and Results at 313.15 K and Atmospheric Pressure |
title_short | Excess Enthalpies for Binary Mixtures of the Reactive System Acetic Acid + n-Butanol + n-Butyl Acetate + Water: Brief Data Review and Results at 313.15 K and Atmospheric Pressure |
title_sort | excess enthalpies for binary mixtures of the reactive system acetic acid + n-butanol + n-butyl acetate + water: brief data review and results at 313.15 k and atmospheric pressure |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10048811/ https://www.ncbi.nlm.nih.gov/pubmed/36982213 http://dx.doi.org/10.3390/ijms24065137 |
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