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Excess Enthalpies for Binary Mixtures of the Reactive System Acetic Acid + n-Butanol + n-Butyl Acetate + Water: Brief Data Review and Results at 313.15 K and Atmospheric Pressure

The data on molar excess enthalpies, [Formula: see text] , for the binary mixtures acetic acid + n-butanol, acetic acid + n-butyl acetate and n-butanol + n-butyl acetate at 313.15 K and atmospheric pressure were obtained with use of the C80 isothermal mixing calorimeter (Setaram). The correlation of...

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Autores principales: Golikova, Alexandra, Shasherina, Anna, Anufrikov, Yuri, Misikov, Georgii, Toikka, Maria, Zvereva, Irina, Toikka, Alexander
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10048811/
https://www.ncbi.nlm.nih.gov/pubmed/36982213
http://dx.doi.org/10.3390/ijms24065137
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author Golikova, Alexandra
Shasherina, Anna
Anufrikov, Yuri
Misikov, Georgii
Toikka, Maria
Zvereva, Irina
Toikka, Alexander
author_facet Golikova, Alexandra
Shasherina, Anna
Anufrikov, Yuri
Misikov, Georgii
Toikka, Maria
Zvereva, Irina
Toikka, Alexander
author_sort Golikova, Alexandra
collection PubMed
description The data on molar excess enthalpies, [Formula: see text] , for the binary mixtures acetic acid + n-butanol, acetic acid + n-butyl acetate and n-butanol + n-butyl acetate at 313.15 K and atmospheric pressure were obtained with use of the C80 isothermal mixing calorimeter (Setaram). The correlation of the data was carried out using the NRTL model and Redlich–Kister equation. A comparative analysis with the literature data on all available binary subsystems of the quaternary system was carried out. Other thermodynamic properties ([Formula: see text] , [Formula: see text] , [Formula: see text] , [Formula: see text] and [Formula: see text]) of the binary systems were estimated using literature data and well-known formulas of classical thermodynamics.
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spelling pubmed-100488112023-03-29 Excess Enthalpies for Binary Mixtures of the Reactive System Acetic Acid + n-Butanol + n-Butyl Acetate + Water: Brief Data Review and Results at 313.15 K and Atmospheric Pressure Golikova, Alexandra Shasherina, Anna Anufrikov, Yuri Misikov, Georgii Toikka, Maria Zvereva, Irina Toikka, Alexander Int J Mol Sci Article The data on molar excess enthalpies, [Formula: see text] , for the binary mixtures acetic acid + n-butanol, acetic acid + n-butyl acetate and n-butanol + n-butyl acetate at 313.15 K and atmospheric pressure were obtained with use of the C80 isothermal mixing calorimeter (Setaram). The correlation of the data was carried out using the NRTL model and Redlich–Kister equation. A comparative analysis with the literature data on all available binary subsystems of the quaternary system was carried out. Other thermodynamic properties ([Formula: see text] , [Formula: see text] , [Formula: see text] , [Formula: see text] and [Formula: see text]) of the binary systems were estimated using literature data and well-known formulas of classical thermodynamics. MDPI 2023-03-07 /pmc/articles/PMC10048811/ /pubmed/36982213 http://dx.doi.org/10.3390/ijms24065137 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Golikova, Alexandra
Shasherina, Anna
Anufrikov, Yuri
Misikov, Georgii
Toikka, Maria
Zvereva, Irina
Toikka, Alexander
Excess Enthalpies for Binary Mixtures of the Reactive System Acetic Acid + n-Butanol + n-Butyl Acetate + Water: Brief Data Review and Results at 313.15 K and Atmospheric Pressure
title Excess Enthalpies for Binary Mixtures of the Reactive System Acetic Acid + n-Butanol + n-Butyl Acetate + Water: Brief Data Review and Results at 313.15 K and Atmospheric Pressure
title_full Excess Enthalpies for Binary Mixtures of the Reactive System Acetic Acid + n-Butanol + n-Butyl Acetate + Water: Brief Data Review and Results at 313.15 K and Atmospheric Pressure
title_fullStr Excess Enthalpies for Binary Mixtures of the Reactive System Acetic Acid + n-Butanol + n-Butyl Acetate + Water: Brief Data Review and Results at 313.15 K and Atmospheric Pressure
title_full_unstemmed Excess Enthalpies for Binary Mixtures of the Reactive System Acetic Acid + n-Butanol + n-Butyl Acetate + Water: Brief Data Review and Results at 313.15 K and Atmospheric Pressure
title_short Excess Enthalpies for Binary Mixtures of the Reactive System Acetic Acid + n-Butanol + n-Butyl Acetate + Water: Brief Data Review and Results at 313.15 K and Atmospheric Pressure
title_sort excess enthalpies for binary mixtures of the reactive system acetic acid + n-butanol + n-butyl acetate + water: brief data review and results at 313.15 k and atmospheric pressure
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10048811/
https://www.ncbi.nlm.nih.gov/pubmed/36982213
http://dx.doi.org/10.3390/ijms24065137
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