A Hydrocarbon Soluble, Molecular and “Complete” Al-Cocatalyst for High Temperature Olefin Polymerization

The dinuclear aluminum salt {[iBu(2)(DMA)Al](2)(μ-H)}(+)[B(C(6)F(5))(4)](−) (AlHAl; DMA = N,N-dimethylaniline) is the prototype of a new class of molecular cocatalysts for catalytic olefin polymerization, its modular nature offering easy avenues for tailoring the activator to specific needs. We repo...

Descripción completa

Detalles Bibliográficos
Autores principales: Urciuoli, Gaia, Zaccaria, Francesco, Zuccaccia, Cristiano, Cipullo, Roberta, Budzelaar, Peter H. M., Vittoria, Antonio, Ehm, Christian, Macchioni, Alceo, Busico, Vincenzo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10051415/
https://www.ncbi.nlm.nih.gov/pubmed/36987158
http://dx.doi.org/10.3390/polym15061378
_version_ 1785014880633356288
author Urciuoli, Gaia
Zaccaria, Francesco
Zuccaccia, Cristiano
Cipullo, Roberta
Budzelaar, Peter H. M.
Vittoria, Antonio
Ehm, Christian
Macchioni, Alceo
Busico, Vincenzo
author_facet Urciuoli, Gaia
Zaccaria, Francesco
Zuccaccia, Cristiano
Cipullo, Roberta
Budzelaar, Peter H. M.
Vittoria, Antonio
Ehm, Christian
Macchioni, Alceo
Busico, Vincenzo
author_sort Urciuoli, Gaia
collection PubMed
description The dinuclear aluminum salt {[iBu(2)(DMA)Al](2)(μ-H)}(+)[B(C(6)F(5))(4)](−) (AlHAl; DMA = N,N-dimethylaniline) is the prototype of a new class of molecular cocatalysts for catalytic olefin polymerization, its modular nature offering easy avenues for tailoring the activator to specific needs. We report here, as proof of concept, a first variant (s-AlHAl) bearing p-hexadecyl-N,N-dimethylaniline (DMA(C16)) units, which enhances solubility in aliphatic hydrocarbons. The novel s-AlHAl was used successfully as an activator/scavenger in ethylene/1-hexene copolymerization in a high-temperature solution process.
format Online
Article
Text
id pubmed-10051415
institution National Center for Biotechnology Information
language English
publishDate 2023
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-100514152023-03-30 A Hydrocarbon Soluble, Molecular and “Complete” Al-Cocatalyst for High Temperature Olefin Polymerization Urciuoli, Gaia Zaccaria, Francesco Zuccaccia, Cristiano Cipullo, Roberta Budzelaar, Peter H. M. Vittoria, Antonio Ehm, Christian Macchioni, Alceo Busico, Vincenzo Polymers (Basel) Article The dinuclear aluminum salt {[iBu(2)(DMA)Al](2)(μ-H)}(+)[B(C(6)F(5))(4)](−) (AlHAl; DMA = N,N-dimethylaniline) is the prototype of a new class of molecular cocatalysts for catalytic olefin polymerization, its modular nature offering easy avenues for tailoring the activator to specific needs. We report here, as proof of concept, a first variant (s-AlHAl) bearing p-hexadecyl-N,N-dimethylaniline (DMA(C16)) units, which enhances solubility in aliphatic hydrocarbons. The novel s-AlHAl was used successfully as an activator/scavenger in ethylene/1-hexene copolymerization in a high-temperature solution process. MDPI 2023-03-09 /pmc/articles/PMC10051415/ /pubmed/36987158 http://dx.doi.org/10.3390/polym15061378 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Urciuoli, Gaia
Zaccaria, Francesco
Zuccaccia, Cristiano
Cipullo, Roberta
Budzelaar, Peter H. M.
Vittoria, Antonio
Ehm, Christian
Macchioni, Alceo
Busico, Vincenzo
A Hydrocarbon Soluble, Molecular and “Complete” Al-Cocatalyst for High Temperature Olefin Polymerization
title A Hydrocarbon Soluble, Molecular and “Complete” Al-Cocatalyst for High Temperature Olefin Polymerization
title_full A Hydrocarbon Soluble, Molecular and “Complete” Al-Cocatalyst for High Temperature Olefin Polymerization
title_fullStr A Hydrocarbon Soluble, Molecular and “Complete” Al-Cocatalyst for High Temperature Olefin Polymerization
title_full_unstemmed A Hydrocarbon Soluble, Molecular and “Complete” Al-Cocatalyst for High Temperature Olefin Polymerization
title_short A Hydrocarbon Soluble, Molecular and “Complete” Al-Cocatalyst for High Temperature Olefin Polymerization
title_sort hydrocarbon soluble, molecular and “complete” al-cocatalyst for high temperature olefin polymerization
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10051415/
https://www.ncbi.nlm.nih.gov/pubmed/36987158
http://dx.doi.org/10.3390/polym15061378
work_keys_str_mv AT urciuoligaia ahydrocarbonsolublemolecularandcompletealcocatalystforhightemperatureolefinpolymerization
AT zaccariafrancesco ahydrocarbonsolublemolecularandcompletealcocatalystforhightemperatureolefinpolymerization
AT zuccacciacristiano ahydrocarbonsolublemolecularandcompletealcocatalystforhightemperatureolefinpolymerization
AT cipulloroberta ahydrocarbonsolublemolecularandcompletealcocatalystforhightemperatureolefinpolymerization
AT budzelaarpeterhm ahydrocarbonsolublemolecularandcompletealcocatalystforhightemperatureolefinpolymerization
AT vittoriaantonio ahydrocarbonsolublemolecularandcompletealcocatalystforhightemperatureolefinpolymerization
AT ehmchristian ahydrocarbonsolublemolecularandcompletealcocatalystforhightemperatureolefinpolymerization
AT macchionialceo ahydrocarbonsolublemolecularandcompletealcocatalystforhightemperatureolefinpolymerization
AT busicovincenzo ahydrocarbonsolublemolecularandcompletealcocatalystforhightemperatureolefinpolymerization
AT urciuoligaia hydrocarbonsolublemolecularandcompletealcocatalystforhightemperatureolefinpolymerization
AT zaccariafrancesco hydrocarbonsolublemolecularandcompletealcocatalystforhightemperatureolefinpolymerization
AT zuccacciacristiano hydrocarbonsolublemolecularandcompletealcocatalystforhightemperatureolefinpolymerization
AT cipulloroberta hydrocarbonsolublemolecularandcompletealcocatalystforhightemperatureolefinpolymerization
AT budzelaarpeterhm hydrocarbonsolublemolecularandcompletealcocatalystforhightemperatureolefinpolymerization
AT vittoriaantonio hydrocarbonsolublemolecularandcompletealcocatalystforhightemperatureolefinpolymerization
AT ehmchristian hydrocarbonsolublemolecularandcompletealcocatalystforhightemperatureolefinpolymerization
AT macchionialceo hydrocarbonsolublemolecularandcompletealcocatalystforhightemperatureolefinpolymerization
AT busicovincenzo hydrocarbonsolublemolecularandcompletealcocatalystforhightemperatureolefinpolymerization

Ejemplares similares