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Assimilation of Nanoparticles of SiC, ZrC, and WC with Polyaryletherketone for Performance Augmentation of Adhesives
The present paper reports the analyses of results obtained from experiments carried out to explore the challenge of homogeneous, uniform, and deagglomerated dispersion of ultra-heavy nanoparticles (NPs) in the high-performance polyaryletherketone (PAEK) matrix. An equal and fixed amount of (0.5 vol....
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10051567/ https://www.ncbi.nlm.nih.gov/pubmed/36985922 http://dx.doi.org/10.3390/nano13061028 |
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author | Marathe, Umesh Bijwe, Jayashree |
author_facet | Marathe, Umesh Bijwe, Jayashree |
author_sort | Marathe, Umesh |
collection | PubMed |
description | The present paper reports the analyses of results obtained from experiments carried out to explore the challenge of homogeneous, uniform, and deagglomerated dispersion of ultra-heavy nanoparticles (NPs) in the high-performance polyaryletherketone (PAEK) matrix. An equal and fixed amount of (0.5 vol. %) NPs of silicon carbide (SiC), zirconium carbide (ZrC), and tungsten carbide (WC) were dispersed in a PAEK matrix and compression molded to develop three different nanocomposites. Simultaneously, nano-adhesives of the same composition were also developed to join the stainless steel adherends. The composites and adhesives were characterized for their physical, thermal, thermo-mechanical, thermal conductivity (TC), and lap shear strength (LSS) behavior. It was observed that SiC NPs performed significantly better than ZrC and WC NCs in all performance properties (LSS: 154%, TC: 263%, tensile strength: 21%). Thermal conductivity (TC) and tensile properties were validated using various predictive models, such as the rule of mixture parallel model, the Chiew and Glandt model, and the Lewis model. Scanning electron micrographs were used for the morphological analysis of LSS samples to detect macro- and micro-failure. Micrographs showed evidence of micro-striation and plastic deformation as a micromodel, as well as mixed failure, i.e., adhesive–cohesive as a macro-failure mode. |
format | Online Article Text |
id | pubmed-10051567 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-100515672023-03-30 Assimilation of Nanoparticles of SiC, ZrC, and WC with Polyaryletherketone for Performance Augmentation of Adhesives Marathe, Umesh Bijwe, Jayashree Nanomaterials (Basel) Article The present paper reports the analyses of results obtained from experiments carried out to explore the challenge of homogeneous, uniform, and deagglomerated dispersion of ultra-heavy nanoparticles (NPs) in the high-performance polyaryletherketone (PAEK) matrix. An equal and fixed amount of (0.5 vol. %) NPs of silicon carbide (SiC), zirconium carbide (ZrC), and tungsten carbide (WC) were dispersed in a PAEK matrix and compression molded to develop three different nanocomposites. Simultaneously, nano-adhesives of the same composition were also developed to join the stainless steel adherends. The composites and adhesives were characterized for their physical, thermal, thermo-mechanical, thermal conductivity (TC), and lap shear strength (LSS) behavior. It was observed that SiC NPs performed significantly better than ZrC and WC NCs in all performance properties (LSS: 154%, TC: 263%, tensile strength: 21%). Thermal conductivity (TC) and tensile properties were validated using various predictive models, such as the rule of mixture parallel model, the Chiew and Glandt model, and the Lewis model. Scanning electron micrographs were used for the morphological analysis of LSS samples to detect macro- and micro-failure. Micrographs showed evidence of micro-striation and plastic deformation as a micromodel, as well as mixed failure, i.e., adhesive–cohesive as a macro-failure mode. MDPI 2023-03-13 /pmc/articles/PMC10051567/ /pubmed/36985922 http://dx.doi.org/10.3390/nano13061028 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Marathe, Umesh Bijwe, Jayashree Assimilation of Nanoparticles of SiC, ZrC, and WC with Polyaryletherketone for Performance Augmentation of Adhesives |
title | Assimilation of Nanoparticles of SiC, ZrC, and WC with Polyaryletherketone for Performance Augmentation of Adhesives |
title_full | Assimilation of Nanoparticles of SiC, ZrC, and WC with Polyaryletherketone for Performance Augmentation of Adhesives |
title_fullStr | Assimilation of Nanoparticles of SiC, ZrC, and WC with Polyaryletherketone for Performance Augmentation of Adhesives |
title_full_unstemmed | Assimilation of Nanoparticles of SiC, ZrC, and WC with Polyaryletherketone for Performance Augmentation of Adhesives |
title_short | Assimilation of Nanoparticles of SiC, ZrC, and WC with Polyaryletherketone for Performance Augmentation of Adhesives |
title_sort | assimilation of nanoparticles of sic, zrc, and wc with polyaryletherketone for performance augmentation of adhesives |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10051567/ https://www.ncbi.nlm.nih.gov/pubmed/36985922 http://dx.doi.org/10.3390/nano13061028 |
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