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Vanadium Extraction from the Flotation Concentrate of Vanadium-Bearing Shale by Process of Non-Roasting Enhanced Acid Leaching and Thermodynamics
The purpose of this work is to significantly improve the vanadium grade of vanadium-bearing shale after flotation preconcentration, which is conducive to reducing the acid consumption and industrial costs in the subsequently enhanced acid leaching of vanadium. Vanadium concentrate from vanadium-bear...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10052970/ https://www.ncbi.nlm.nih.gov/pubmed/36985678 http://dx.doi.org/10.3390/molecules28062706 |
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author | Tang, Yue Ye, Guohua Zuo, Qi |
author_facet | Tang, Yue Ye, Guohua Zuo, Qi |
author_sort | Tang, Yue |
collection | PubMed |
description | The purpose of this work is to significantly improve the vanadium grade of vanadium-bearing shale after flotation preconcentration, which is conducive to reducing the acid consumption and industrial costs in the subsequently enhanced acid leaching of vanadium. Vanadium concentrate from vanadium-bearing shale enriched by flotation is used for acid-leaching feed. The leaching effects of two kinds of acid-leaching systems were compared, and the mechanism of acid leaching on the mineral structure was also described. The difficulty of spontaneous reactions of vanadium-bearing minerals such as garnet in an acid-leaching system was studied through thermodynamics. Additionally, several characterization methods were used to evaluate the improvement of leaching performance. The addition of oxidants and fluorinating aids strengthens the acid-leaching process, which greatly destroys the structure of a garnet, which is conducive to the extraction of vanadium in a flotation concentrate. The leaching efficiency can reach 94.86%, and the acid consumption is also reduced. Through the mechanism study of the leaching system, it is expected that when the enhanced acid-leaching process is put into industrial production, the effective leaching of vanadium can be accurately controlled, and the difficulty of subsequent vanadium enrichment and purification can be reduced. |
format | Online Article Text |
id | pubmed-10052970 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-100529702023-03-30 Vanadium Extraction from the Flotation Concentrate of Vanadium-Bearing Shale by Process of Non-Roasting Enhanced Acid Leaching and Thermodynamics Tang, Yue Ye, Guohua Zuo, Qi Molecules Article The purpose of this work is to significantly improve the vanadium grade of vanadium-bearing shale after flotation preconcentration, which is conducive to reducing the acid consumption and industrial costs in the subsequently enhanced acid leaching of vanadium. Vanadium concentrate from vanadium-bearing shale enriched by flotation is used for acid-leaching feed. The leaching effects of two kinds of acid-leaching systems were compared, and the mechanism of acid leaching on the mineral structure was also described. The difficulty of spontaneous reactions of vanadium-bearing minerals such as garnet in an acid-leaching system was studied through thermodynamics. Additionally, several characterization methods were used to evaluate the improvement of leaching performance. The addition of oxidants and fluorinating aids strengthens the acid-leaching process, which greatly destroys the structure of a garnet, which is conducive to the extraction of vanadium in a flotation concentrate. The leaching efficiency can reach 94.86%, and the acid consumption is also reduced. Through the mechanism study of the leaching system, it is expected that when the enhanced acid-leaching process is put into industrial production, the effective leaching of vanadium can be accurately controlled, and the difficulty of subsequent vanadium enrichment and purification can be reduced. MDPI 2023-03-16 /pmc/articles/PMC10052970/ /pubmed/36985678 http://dx.doi.org/10.3390/molecules28062706 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Tang, Yue Ye, Guohua Zuo, Qi Vanadium Extraction from the Flotation Concentrate of Vanadium-Bearing Shale by Process of Non-Roasting Enhanced Acid Leaching and Thermodynamics |
title | Vanadium Extraction from the Flotation Concentrate of Vanadium-Bearing Shale by Process of Non-Roasting Enhanced Acid Leaching and Thermodynamics |
title_full | Vanadium Extraction from the Flotation Concentrate of Vanadium-Bearing Shale by Process of Non-Roasting Enhanced Acid Leaching and Thermodynamics |
title_fullStr | Vanadium Extraction from the Flotation Concentrate of Vanadium-Bearing Shale by Process of Non-Roasting Enhanced Acid Leaching and Thermodynamics |
title_full_unstemmed | Vanadium Extraction from the Flotation Concentrate of Vanadium-Bearing Shale by Process of Non-Roasting Enhanced Acid Leaching and Thermodynamics |
title_short | Vanadium Extraction from the Flotation Concentrate of Vanadium-Bearing Shale by Process of Non-Roasting Enhanced Acid Leaching and Thermodynamics |
title_sort | vanadium extraction from the flotation concentrate of vanadium-bearing shale by process of non-roasting enhanced acid leaching and thermodynamics |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10052970/ https://www.ncbi.nlm.nih.gov/pubmed/36985678 http://dx.doi.org/10.3390/molecules28062706 |
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