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A Facile Microwave Hydrothermal Synthesis of ZnFe(2)O(4)/rGO Nanocomposites for Supercapacitor Electrodes

As a typical binary transition metal oxide, ZnFe(2)O(4) has attracted considerable attention for supercapacitor electrodes due to its high theoretical specific capacitance. However, the reported synthesis processes of ZnFe(2)O(4) are complicated and ZnFe(2)O(4) nanoparticles are easily agglomerated,...

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Autores principales: Mo, Xiaoyao, Xu, Guangxu, Kang, Xiaochan, Yin, Hang, Cui, Xiaochen, Zhao, Yuling, Zhang, Jianmin, Tang, Jie, Wang, Fengyun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10053183/
https://www.ncbi.nlm.nih.gov/pubmed/36985927
http://dx.doi.org/10.3390/nano13061034
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author Mo, Xiaoyao
Xu, Guangxu
Kang, Xiaochan
Yin, Hang
Cui, Xiaochen
Zhao, Yuling
Zhang, Jianmin
Tang, Jie
Wang, Fengyun
author_facet Mo, Xiaoyao
Xu, Guangxu
Kang, Xiaochan
Yin, Hang
Cui, Xiaochen
Zhao, Yuling
Zhang, Jianmin
Tang, Jie
Wang, Fengyun
author_sort Mo, Xiaoyao
collection PubMed
description As a typical binary transition metal oxide, ZnFe(2)O(4) has attracted considerable attention for supercapacitor electrodes due to its high theoretical specific capacitance. However, the reported synthesis processes of ZnFe(2)O(4) are complicated and ZnFe(2)O(4) nanoparticles are easily agglomerated, leading to poor cycle life and unfavorable capacity. Herein, a facile microwave hydrothermal process was used to prepare ZnFe(2)O(4)/reduced graphene oxide (rGO) nanocomposites in this work. The influence of rGO content on the morphology, structure, and electrochemical performance of ZnFe(2)O(4)/rGO nanocomposites was systematically investigated. Due to the uniform distribution of ZnFe(2)O(4) nanoparticles on the rGO surface and the high specific surface area and rich pore structures, the as-prepared ZnFe(2)O(4)/rGO electrode with 44.3 wt.% rGO content exhibits a high specific capacitance of 628 F g(−1) and long cycle life of 89% retention over 2500 cycles at 1 A g(−1). This work provides a new process for synthesizing binary transition metal oxide and developing a new strategy for realizing high-performance composites for supercapacitor electrodes.
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spelling pubmed-100531832023-03-30 A Facile Microwave Hydrothermal Synthesis of ZnFe(2)O(4)/rGO Nanocomposites for Supercapacitor Electrodes Mo, Xiaoyao Xu, Guangxu Kang, Xiaochan Yin, Hang Cui, Xiaochen Zhao, Yuling Zhang, Jianmin Tang, Jie Wang, Fengyun Nanomaterials (Basel) Article As a typical binary transition metal oxide, ZnFe(2)O(4) has attracted considerable attention for supercapacitor electrodes due to its high theoretical specific capacitance. However, the reported synthesis processes of ZnFe(2)O(4) are complicated and ZnFe(2)O(4) nanoparticles are easily agglomerated, leading to poor cycle life and unfavorable capacity. Herein, a facile microwave hydrothermal process was used to prepare ZnFe(2)O(4)/reduced graphene oxide (rGO) nanocomposites in this work. The influence of rGO content on the morphology, structure, and electrochemical performance of ZnFe(2)O(4)/rGO nanocomposites was systematically investigated. Due to the uniform distribution of ZnFe(2)O(4) nanoparticles on the rGO surface and the high specific surface area and rich pore structures, the as-prepared ZnFe(2)O(4)/rGO electrode with 44.3 wt.% rGO content exhibits a high specific capacitance of 628 F g(−1) and long cycle life of 89% retention over 2500 cycles at 1 A g(−1). This work provides a new process for synthesizing binary transition metal oxide and developing a new strategy for realizing high-performance composites for supercapacitor electrodes. MDPI 2023-03-13 /pmc/articles/PMC10053183/ /pubmed/36985927 http://dx.doi.org/10.3390/nano13061034 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Mo, Xiaoyao
Xu, Guangxu
Kang, Xiaochan
Yin, Hang
Cui, Xiaochen
Zhao, Yuling
Zhang, Jianmin
Tang, Jie
Wang, Fengyun
A Facile Microwave Hydrothermal Synthesis of ZnFe(2)O(4)/rGO Nanocomposites for Supercapacitor Electrodes
title A Facile Microwave Hydrothermal Synthesis of ZnFe(2)O(4)/rGO Nanocomposites for Supercapacitor Electrodes
title_full A Facile Microwave Hydrothermal Synthesis of ZnFe(2)O(4)/rGO Nanocomposites for Supercapacitor Electrodes
title_fullStr A Facile Microwave Hydrothermal Synthesis of ZnFe(2)O(4)/rGO Nanocomposites for Supercapacitor Electrodes
title_full_unstemmed A Facile Microwave Hydrothermal Synthesis of ZnFe(2)O(4)/rGO Nanocomposites for Supercapacitor Electrodes
title_short A Facile Microwave Hydrothermal Synthesis of ZnFe(2)O(4)/rGO Nanocomposites for Supercapacitor Electrodes
title_sort facile microwave hydrothermal synthesis of znfe(2)o(4)/rgo nanocomposites for supercapacitor electrodes
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10053183/
https://www.ncbi.nlm.nih.gov/pubmed/36985927
http://dx.doi.org/10.3390/nano13061034
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