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Brønsted Acid versus Phase‐Transfer Catalysis in the Enantioselective Transannular Aminohalogenation of Enesultams

We have studied the enantioselective transannular aminohalogenation reaction of unsaturated medium‐sized cyclic benzosulfonamides by using both chiral Brønsted acid and phase‐transfer catalysis. Under optimized conditions, a variety of bicyclic adducts can be obtained with good yields and high enant...

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Detalles Bibliográficos
Autores principales: Luis‐Barrera, Javier, Rodriguez, Sandra, Uria, Uxue, Reyes, Efraim, Prieto, Liher, Carrillo, Luisa, Pedrón, Manuel, Tejero, Tomás, Merino, Pedro, Vicario, Jose L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10053555/
https://www.ncbi.nlm.nih.gov/pubmed/36111677
http://dx.doi.org/10.1002/chem.202202267