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MDACl(2)-Modified SnO(2) Film for Efficient Planar Perovskite Solar Cells

The electron transport layer (ETL) with excellent charge extraction and transport ability is one of the key components of high-performance perovskite solar cells (PSCs). SnO(2) has been considered as a more promising ETL for the future commercialization of PSCs due to its excellent photoelectric pro...

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Autores principales: Xiao, Yaodong, Cui, Xiangqian, Xiang, Boyuan, Chen, Yanping, Zhao, Chaoyue, Wang, Lihong, Yang, Chuqun, Zhang, Guangye, Xie, Chen, Han, Yulai, Qiu, Mingxia, Li, Shunpu, You, Peng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10056177/
https://www.ncbi.nlm.nih.gov/pubmed/36985640
http://dx.doi.org/10.3390/molecules28062668
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author Xiao, Yaodong
Cui, Xiangqian
Xiang, Boyuan
Chen, Yanping
Zhao, Chaoyue
Wang, Lihong
Yang, Chuqun
Zhang, Guangye
Xie, Chen
Han, Yulai
Qiu, Mingxia
Li, Shunpu
You, Peng
author_facet Xiao, Yaodong
Cui, Xiangqian
Xiang, Boyuan
Chen, Yanping
Zhao, Chaoyue
Wang, Lihong
Yang, Chuqun
Zhang, Guangye
Xie, Chen
Han, Yulai
Qiu, Mingxia
Li, Shunpu
You, Peng
author_sort Xiao, Yaodong
collection PubMed
description The electron transport layer (ETL) with excellent charge extraction and transport ability is one of the key components of high-performance perovskite solar cells (PSCs). SnO(2) has been considered as a more promising ETL for the future commercialization of PSCs due to its excellent photoelectric properties and easy processing. Herein, we propose a facile and effective ETL modification strategy based on the incorporation of methylenediammonium dichloride (MDACl(2)) into the SnO(2) precursor colloidal solution. The effects of MDACl(2) incorporation on charge transport, defect passivation, perovskite crystallization, and PSC performance are systematically investigated. First, the surface defects of the SnO(2) film are effectively passivated, resulting in the increased conductivity of the SnO(2) film, which is conducive to electron extraction and transport. Second, the MDACl(2) modification contributes to the formation of high-quality perovskite films with improved crystallinity and reduced defect density. Furthermore, a more suitable energy level alignment is achieved at the ETL/perovskite interface, which facilitates the charge transport due to the lower energy barrier. Consequently, the MDACl(2)-modified PSCs exhibit a champion efficiency of 22.30% compared with 19.62% of the control device, and the device stability is also significantly improved.
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spelling pubmed-100561772023-03-30 MDACl(2)-Modified SnO(2) Film for Efficient Planar Perovskite Solar Cells Xiao, Yaodong Cui, Xiangqian Xiang, Boyuan Chen, Yanping Zhao, Chaoyue Wang, Lihong Yang, Chuqun Zhang, Guangye Xie, Chen Han, Yulai Qiu, Mingxia Li, Shunpu You, Peng Molecules Article The electron transport layer (ETL) with excellent charge extraction and transport ability is one of the key components of high-performance perovskite solar cells (PSCs). SnO(2) has been considered as a more promising ETL for the future commercialization of PSCs due to its excellent photoelectric properties and easy processing. Herein, we propose a facile and effective ETL modification strategy based on the incorporation of methylenediammonium dichloride (MDACl(2)) into the SnO(2) precursor colloidal solution. The effects of MDACl(2) incorporation on charge transport, defect passivation, perovskite crystallization, and PSC performance are systematically investigated. First, the surface defects of the SnO(2) film are effectively passivated, resulting in the increased conductivity of the SnO(2) film, which is conducive to electron extraction and transport. Second, the MDACl(2) modification contributes to the formation of high-quality perovskite films with improved crystallinity and reduced defect density. Furthermore, a more suitable energy level alignment is achieved at the ETL/perovskite interface, which facilitates the charge transport due to the lower energy barrier. Consequently, the MDACl(2)-modified PSCs exhibit a champion efficiency of 22.30% compared with 19.62% of the control device, and the device stability is also significantly improved. MDPI 2023-03-15 /pmc/articles/PMC10056177/ /pubmed/36985640 http://dx.doi.org/10.3390/molecules28062668 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Xiao, Yaodong
Cui, Xiangqian
Xiang, Boyuan
Chen, Yanping
Zhao, Chaoyue
Wang, Lihong
Yang, Chuqun
Zhang, Guangye
Xie, Chen
Han, Yulai
Qiu, Mingxia
Li, Shunpu
You, Peng
MDACl(2)-Modified SnO(2) Film for Efficient Planar Perovskite Solar Cells
title MDACl(2)-Modified SnO(2) Film for Efficient Planar Perovskite Solar Cells
title_full MDACl(2)-Modified SnO(2) Film for Efficient Planar Perovskite Solar Cells
title_fullStr MDACl(2)-Modified SnO(2) Film for Efficient Planar Perovskite Solar Cells
title_full_unstemmed MDACl(2)-Modified SnO(2) Film for Efficient Planar Perovskite Solar Cells
title_short MDACl(2)-Modified SnO(2) Film for Efficient Planar Perovskite Solar Cells
title_sort mdacl(2)-modified sno(2) film for efficient planar perovskite solar cells
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10056177/
https://www.ncbi.nlm.nih.gov/pubmed/36985640
http://dx.doi.org/10.3390/molecules28062668
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