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Ring Opening Polymerization Used for the Production of VOC Free High-Performance Ecofriendly Novel PBZ/PDA/CeO(2) Nanocomposites
This study analyzed the fabrication and characterization of polybenzoxazine/polydopamine/ceria as tertiary nanocomposites. To this end, a new benzoxazine monomer (MBZ) was fabricated based on the well-known Mannich reaction of naphthalene-1-amine, 2-tert-butylbenzene-1,4-diol and formaldehyde under...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10057122/ https://www.ncbi.nlm.nih.gov/pubmed/36987197 http://dx.doi.org/10.3390/polym15061416 |
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author | Hatami, Mehdi Abadi, Zohreh Seifi Najaf Yousefi, Alireza Qandalee, Mohammad Djafarzadeh, Nader Ghasemi, Yaser López-Coca, Ignacio M. Durán-Valle, Carlos J. |
author_facet | Hatami, Mehdi Abadi, Zohreh Seifi Najaf Yousefi, Alireza Qandalee, Mohammad Djafarzadeh, Nader Ghasemi, Yaser López-Coca, Ignacio M. Durán-Valle, Carlos J. |
author_sort | Hatami, Mehdi |
collection | PubMed |
description | This study analyzed the fabrication and characterization of polybenzoxazine/polydopamine/ceria as tertiary nanocomposites. To this end, a new benzoxazine monomer (MBZ) was fabricated based on the well-known Mannich reaction of naphthalene-1-amine, 2-tert-butylbenzene-1,4-diol and formaldehyde under ultrasonic-assisted process. Polydopamine (PDA) was used as dispersing polymer nanoparticles and surface modifier for CeO(2) by in-situ polymerization of dopamine with the assistance of ultrasonic waves. Then, nanocomposites (NC)s were manufactured by in-situ route under thermal conditions. The FT-IR and (1)H-NMR spectra confirmed the preparation of the designed MBZ monomer. The FE-SEM and TEM results showed the morphological aspects of prepared NCs and illustrated the distribution of CeO(2) NPs in the polymer matrix. The XRD patterns of NCs showed the presence of crystalline phases of nanoscale CeO(2) in an amorphous matrix. The TGA results reveal that the prepared NCs are classified as thermally stable materials. |
format | Online Article Text |
id | pubmed-10057122 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-100571222023-03-30 Ring Opening Polymerization Used for the Production of VOC Free High-Performance Ecofriendly Novel PBZ/PDA/CeO(2) Nanocomposites Hatami, Mehdi Abadi, Zohreh Seifi Najaf Yousefi, Alireza Qandalee, Mohammad Djafarzadeh, Nader Ghasemi, Yaser López-Coca, Ignacio M. Durán-Valle, Carlos J. Polymers (Basel) Article This study analyzed the fabrication and characterization of polybenzoxazine/polydopamine/ceria as tertiary nanocomposites. To this end, a new benzoxazine monomer (MBZ) was fabricated based on the well-known Mannich reaction of naphthalene-1-amine, 2-tert-butylbenzene-1,4-diol and formaldehyde under ultrasonic-assisted process. Polydopamine (PDA) was used as dispersing polymer nanoparticles and surface modifier for CeO(2) by in-situ polymerization of dopamine with the assistance of ultrasonic waves. Then, nanocomposites (NC)s were manufactured by in-situ route under thermal conditions. The FT-IR and (1)H-NMR spectra confirmed the preparation of the designed MBZ monomer. The FE-SEM and TEM results showed the morphological aspects of prepared NCs and illustrated the distribution of CeO(2) NPs in the polymer matrix. The XRD patterns of NCs showed the presence of crystalline phases of nanoscale CeO(2) in an amorphous matrix. The TGA results reveal that the prepared NCs are classified as thermally stable materials. MDPI 2023-03-13 /pmc/articles/PMC10057122/ /pubmed/36987197 http://dx.doi.org/10.3390/polym15061416 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Hatami, Mehdi Abadi, Zohreh Seifi Najaf Yousefi, Alireza Qandalee, Mohammad Djafarzadeh, Nader Ghasemi, Yaser López-Coca, Ignacio M. Durán-Valle, Carlos J. Ring Opening Polymerization Used for the Production of VOC Free High-Performance Ecofriendly Novel PBZ/PDA/CeO(2) Nanocomposites |
title | Ring Opening Polymerization Used for the Production of VOC Free High-Performance Ecofriendly Novel PBZ/PDA/CeO(2) Nanocomposites |
title_full | Ring Opening Polymerization Used for the Production of VOC Free High-Performance Ecofriendly Novel PBZ/PDA/CeO(2) Nanocomposites |
title_fullStr | Ring Opening Polymerization Used for the Production of VOC Free High-Performance Ecofriendly Novel PBZ/PDA/CeO(2) Nanocomposites |
title_full_unstemmed | Ring Opening Polymerization Used for the Production of VOC Free High-Performance Ecofriendly Novel PBZ/PDA/CeO(2) Nanocomposites |
title_short | Ring Opening Polymerization Used for the Production of VOC Free High-Performance Ecofriendly Novel PBZ/PDA/CeO(2) Nanocomposites |
title_sort | ring opening polymerization used for the production of voc free high-performance ecofriendly novel pbz/pda/ceo(2) nanocomposites |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10057122/ https://www.ncbi.nlm.nih.gov/pubmed/36987197 http://dx.doi.org/10.3390/polym15061416 |
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