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Sustainable Cauliflower-Patterned CuFe(2)O(4) Electrode Production from Chalcopyrite for Supercapacitor Applications

The primary purpose of this study was to produce an ore-based high-capacity supercapacitor electrode. For this, chalcopyrite ore was first leached with nitric acid, and then metal oxide synthesis was carried out immediately on nickel foam using a hydrothermal technique from the solution. Cauliflower...

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Autores principales: Mbebou, Moctar, Polat, Safa, Zengin, Huseyin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10057429/
https://www.ncbi.nlm.nih.gov/pubmed/36985999
http://dx.doi.org/10.3390/nano13061105
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author Mbebou, Moctar
Polat, Safa
Zengin, Huseyin
author_facet Mbebou, Moctar
Polat, Safa
Zengin, Huseyin
author_sort Mbebou, Moctar
collection PubMed
description The primary purpose of this study was to produce an ore-based high-capacity supercapacitor electrode. For this, chalcopyrite ore was first leached with nitric acid, and then metal oxide synthesis was carried out immediately on nickel foam using a hydrothermal technique from the solution. Cauliflower-patterned CuFe(2)O(4) with a wall thickness of about 23 nm was synthesized on the Ni foam surface, characterized by XRD, FTIR, XPS, SEM, and TEM investigations. The produced electrode also displayed a feature of a battery-like charge storage mechanism with a specific capacity of 525 mF cm(−2) at 2 mA cm(−2) current density, energy of 8.9 mWh cm(−2), and a power density of 233 mW cm(−2). Additionally, even after 1350 cycles, this electrode still performed at 109% of its original capacity. The performance of this finding is 255% higher than that of the CuFe(2)O(4) in our earlier investigation; despite being pure, it performs far better than some of its equivalents in the literature. Obtaining such performance from an electrode made from ore indicates that the use of ore has a lot of potential for supercapacitor production and property improvement.
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spelling pubmed-100574292023-03-30 Sustainable Cauliflower-Patterned CuFe(2)O(4) Electrode Production from Chalcopyrite for Supercapacitor Applications Mbebou, Moctar Polat, Safa Zengin, Huseyin Nanomaterials (Basel) Article The primary purpose of this study was to produce an ore-based high-capacity supercapacitor electrode. For this, chalcopyrite ore was first leached with nitric acid, and then metal oxide synthesis was carried out immediately on nickel foam using a hydrothermal technique from the solution. Cauliflower-patterned CuFe(2)O(4) with a wall thickness of about 23 nm was synthesized on the Ni foam surface, characterized by XRD, FTIR, XPS, SEM, and TEM investigations. The produced electrode also displayed a feature of a battery-like charge storage mechanism with a specific capacity of 525 mF cm(−2) at 2 mA cm(−2) current density, energy of 8.9 mWh cm(−2), and a power density of 233 mW cm(−2). Additionally, even after 1350 cycles, this electrode still performed at 109% of its original capacity. The performance of this finding is 255% higher than that of the CuFe(2)O(4) in our earlier investigation; despite being pure, it performs far better than some of its equivalents in the literature. Obtaining such performance from an electrode made from ore indicates that the use of ore has a lot of potential for supercapacitor production and property improvement. MDPI 2023-03-20 /pmc/articles/PMC10057429/ /pubmed/36985999 http://dx.doi.org/10.3390/nano13061105 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Mbebou, Moctar
Polat, Safa
Zengin, Huseyin
Sustainable Cauliflower-Patterned CuFe(2)O(4) Electrode Production from Chalcopyrite for Supercapacitor Applications
title Sustainable Cauliflower-Patterned CuFe(2)O(4) Electrode Production from Chalcopyrite for Supercapacitor Applications
title_full Sustainable Cauliflower-Patterned CuFe(2)O(4) Electrode Production from Chalcopyrite for Supercapacitor Applications
title_fullStr Sustainable Cauliflower-Patterned CuFe(2)O(4) Electrode Production from Chalcopyrite for Supercapacitor Applications
title_full_unstemmed Sustainable Cauliflower-Patterned CuFe(2)O(4) Electrode Production from Chalcopyrite for Supercapacitor Applications
title_short Sustainable Cauliflower-Patterned CuFe(2)O(4) Electrode Production from Chalcopyrite for Supercapacitor Applications
title_sort sustainable cauliflower-patterned cufe(2)o(4) electrode production from chalcopyrite for supercapacitor applications
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10057429/
https://www.ncbi.nlm.nih.gov/pubmed/36985999
http://dx.doi.org/10.3390/nano13061105
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AT zenginhuseyin sustainablecauliflowerpatternedcufe2o4electrodeproductionfromchalcopyriteforsupercapacitorapplications