Cargando…

Catalytic Properties of Zirconocene-Based Systems in 1-Hexene Oligomerization and Structure of Metal Hydride Reaction Centers

Despite large-scale investigations of homogeneous single-site metallocene catalysts and systems based on them, there are still unsolved problems related to the control of their activity and chemo- and stereoselectivity. A solution to these problems is required to develop efficient methods for the sy...

Descripción completa

Detalles Bibliográficos
Autores principales:	Parfenova, Lyudmila V., Kovyazin, Pavel V., Bikmeeva, Almira Kh., Palatov, Eldar R., Ivchenko, Pavel V., Nifant’ev, Ilya E., Khalilov, Leonard M.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2023
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10058051/ https://www.ncbi.nlm.nih.gov/pubmed/36985393 http://dx.doi.org/10.3390/molecules28062420

Ejemplares similares

Bimetallic Zr,Zr-Hydride Complexes in Zirconocene Catalyzed Alkene Dimerization
por: Parfenova, Lyudmila V., et al.
Publicado: (2020)

Ti Group Metallocene-Catalyzed Synthesis of 1-Hexene Dimers and Tetramers
por: Kovyazin, Pavel V., et al.
Publicado: (2021)

Experimental and Theoretical Study of Zirconocene-Catalyzed Oligomerization of 1-Octene
por: Nifant’ev, Ilya, et al.
Publicado: (2020)

Zirconocene-Catalyzed Dimerization of α-Olefins: DFT Modeling of the Zr-Al Binuclear Reaction Mechanism
por: Nifant’ev, Ilya, et al.
Publicado: (2019)

Fair Look at Coordination Oligomerization of Higher α-Olefins
por: Nifant’ev, Ilya, et al.
Publicado: (2020)

Design, Synthesis and Actual Applications of the Polymers Containing Acidic P–OH Fragments: Part 2—Sidechain Phosphorus-Containing Polyacids
por: Nifant’ev, Ilya E., et al.
Publicado: (2023)

Design, Synthesis and Actual Applications of the Polymers Containing Acidic P–OH Fragments: Part 1. Polyphosphodiesters
por: Nifant’ev, Ilya E., et al.
Publicado: (2022)

MAO- and Borate-Free Activating Supports for Group 4 Metallocene and Post-Metallocene Catalysts of α-Olefin Polymerization and Oligomerization
por: Nifant’ev, Ilya E., et al.
Publicado: (2023)

Coordination Ring-Opening Polymerization of Cyclic Esters: A Critical Overview of DFT Modeling and Visualization of the Reaction Mechanisms
por: Nifant’ev, Ilya, et al.
Publicado: (2019)

DFT Modeling of Organocatalytic Ring-Opening Polymerization of Cyclic Esters: A Crucial Role of Proton Exchange and Hydrogen Bonding
por: Nifant’ev, Ilya, et al.
Publicado: (2019)

Polymer Cold-Flow Improvers for Biodiesel
por: Nifant’ev, Ilya, et al.
Publicado: (2021)

Transition Metal–(μ-Cl)–Aluminum Bonding in α-Olefin and Diene Chemistry
por: Nifant’ev, Ilya E., et al.
Publicado: (2022)

DFT Modeling of the Alternating Radical Copolymerization and Alder-Ene Reaction between Maleic Anhydride and Olefins
por: Nifant’ev, Ilya, et al.
Publicado: (2020)

The Use of Branching Agents in the Synthesis of PBAT
por: Nifant’ev, Ilya E., et al.
Publicado: (2022)

Mechanistic Insights of BHT-Mg-Catalyzed Ethylene Phosphate’s Coordination Ring-Opening Polymerization: DFT Modeling and Experimental Data
por: Nifant’ev, Ilya, et al.
Publicado: (2018)

Comparative Experimental and Theoretical Study of Mg, Al and Zn Aryloxy Complexes in Copolymerization of Cyclic Esters: The Role of the Metal Coordination in Formation of Random Copolymers
por: Nifant’ev, Ilya, et al.
Publicado: (2020)

Data for quantum-chemical modeling of the mechanisms of ring-opening polymerization of methyl ethylene phosphate
por: Nifant'ev, Ilya E., et al.
Publicado: (2019)

DFT Visualization and Experimental Evidence of BHT-Mg-Catalyzed Copolymerization of Lactides, Lactones and Ethylene Phosphates
por: Nifant’ev, Ilya, et al.
Publicado: (2019)

Functionalized Biodegradable Polymers via Termination of Ring-Opening Polymerization by Acyl Chlorides
por: Nifant’ev, Ilya, et al.
Publicado: (2021)

Expanding Zirconocene Hydride Catalysis: In Situ Generation and Turnover of ZrH Catalysts Enabling Catalytic Carbonyl Reductions
por: Kehner, Rebecca A., et al.
Publicado: (2022)

Dispersant and Protective Roles of Amphiphilic Poly(ethylene phosphate) Block Copolymers in Polyester/Bone Mineral Composites
por: Nifant’ev, Ilya, et al.
Publicado: (2023)

In Vitro and In Vivo Studies of Biodegradability and Biocompatibility of Poly(εCL)-b-Poly(EtOEP)-Based Films
por: Nifant’ev, Ilya, et al.
Publicado: (2020)

Antibacterial Poly(ε-CL)/Hydroxyapatite Electrospun Fibers Reinforced by Poly(ε-CL)-b-poly(ethylene phosphoric acid)
por: Nifant’ev, Ilya, et al.
Publicado: (2021)

Tandem Synthesis of Ultra-High Molecular Weight Drag Reducing Poly-α-Olefins for Low-Temperature Pipeline Transportation
por: Nifant’ev, Ilya E., et al.
Publicado: (2021)

The structural diversity of heterocycle-fused potassium cyclopentadienides
por: Nifant'ev, Ilya E., et al.
Publicado: (2019)

Osteogenic Differentiation of Human Adipose Tissue-Derived MSCs by Non-Toxic Calcium Poly(ethylene phosphate)s
por: Nifant’ev, Ilya, et al.
Publicado: (2019)

A New Approach to Developing Long-Acting Injectable Formulations of Anti-HIV Drugs: Poly(Ethylene Phosphoric Acid) Block Copolymers Increase the Efficiency of Tenofovir against HIV-1 in MT-4 Cells
por: Nifant’ev, Ilya, et al.
Publicado: (2020)

Chain-End Functionalization of Poly(ε-caprolactone) for Chemical Binding with Gelatin: Binary Electrospun Scaffolds with Improved Physico-Mechanical Characteristics and Cell Adhesive Properties
por: Nifant’ev, Ilya, et al.
Publicado: (2022)

Mono- and dinuclear zirconocene(iv) amide complexes for the catalytic dehydropolymerisation of phenylsilane
por: Lindenau, Kevin, et al.
Publicado: (2022)

Catalyst Speciation during ansa-Zirconocene-Catalyzed Polymerization of 1-Hexene Studied by UV-vis Spectroscopy—Formation and Partial Re-Activation of Zr-Allyl Intermediates †
por: Panchenko, Valentina N., et al.
Publicado: (2019)

(1R,2S,4r)-1,2,4-Triphenylcyclopentane-1,2-diol and (1R,2S,4r)-4-(2-methoxyphenyl)-1,2-diphenylcyclopentane-1,2-diol: application as initiators for ring-opening polymerization of ∊-caprolactone
por: Komarov, Pavel D., et al.
Publicado: (2019)

Bis[μ-bis(2,6-diisopropylphenyl) phosphato-κ(2) O:O′]bis[(2,2′-bipyridine-κ(2) N,N′)lithium] toluene disolvate and its catalytic activity in ring-opening polymerization of ∊-caprolactone and l-dilactide
por: Kalugin, Alexey E., et al.
Publicado: (2019)

Raman Spectroscopy Study of Structurally Uniform Hydrogenated Oligomers of α-Olefins
por: Kuznetsov, Sergey M., et al.
Publicado: (2020)

Zirconocene catalyzed diastereoselective carbometalation of cyclobutenes
por: Roy, Sudipta Raha, et al.
Publicado: (2017)

Synthesis of zirconocene complexes and their use in slurry-phase polymerisation of ethylene
por: Angpanitcharoen, Phakpoom, et al.
Publicado: (2021)

[4-tert-Butyl-2,6-bis(diphenylmethyl)phenolato-κO]diethyl(tetrahydrofuran-κO)aluminium
por: Minyaev, Mikhail E., et al.
Publicado: (2018)

Crystal structure and catalytic activity of tetrakis(μ(2)-ethyl 2,6-di-tert-butyl-4-methylphenyl phosphato-κ(2) O:O′)bis(ethyl 2,6-di-tert-butyl-4-methylphenyl phosphato-κ(2) O,O′)dilutetium n-heptane disolvate
por: Minyaev, Mikhail E., et al.
Publicado: (2018)

Effects of trans-2-hexenal and cis-3-hexenal on post-harvest strawberry
por: Wakai, Junko, et al.
Publicado: (2019)

Crystal structure of (2,2′-bipyridine-κ(2) N,N′)-trans-bis(tert-butyldimethylsilyloxy)-cis-dioxidomolybdenum(VI)
por: Minyaev, Mikhail E., et al.
Publicado: (2018)

Quasi-Living Polymerization of Propene with an Isotactic-Specific Zirconocene Catalyst
por: Nishii, Kei, et al.
Publicado: (2017)

Cannot write session to /tmp/vufind_sessions/sess_ofb2fblb5dn70cmhi1sr4qu0v8