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Photocatalytic and Antimicrobial Properties of Electrospun TiO(2)–SiO(2)–Al(2)O(3)–ZrO(2)–CaO–CeO(2) Ceramic Membranes

[Image: see text] In this study, TiO(2)-based ceramic nanofiber membranes in the system of TiO(2)–SiO(2)–Al(2)O(3)–ZrO(2)–CaO–CeO(2) were synthesized by combining sol–gel and electrospinning processes. In order to investigate the thermal treatment temperature effect, the obtained nanofiber membranes...

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Autores principales: Yerli Soylu, Nuray, Soylu, Anıl, Dikmetas, Dilara Nur, Karbancioglu-Guler, Funda, Kucukbayrak, Sadriye, Erol Taygun, Melek
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10061526/
https://www.ncbi.nlm.nih.gov/pubmed/37008115
http://dx.doi.org/10.1021/acsomega.2c06986
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author Yerli Soylu, Nuray
Soylu, Anıl
Dikmetas, Dilara Nur
Karbancioglu-Guler, Funda
Kucukbayrak, Sadriye
Erol Taygun, Melek
author_facet Yerli Soylu, Nuray
Soylu, Anıl
Dikmetas, Dilara Nur
Karbancioglu-Guler, Funda
Kucukbayrak, Sadriye
Erol Taygun, Melek
author_sort Yerli Soylu, Nuray
collection PubMed
description [Image: see text] In this study, TiO(2)-based ceramic nanofiber membranes in the system of TiO(2)–SiO(2)–Al(2)O(3)–ZrO(2)–CaO–CeO(2) were synthesized by combining sol–gel and electrospinning processes. In order to investigate the thermal treatment temperature effect, the obtained nanofiber membranes were calcined at different temperatures ranging from 550 to 850 °C. Different characterization methods such as X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared (FT-IR), and high-resolution transmission electron microscopy (HR-TEM) were conducted on the obtained membranes to investigate the structural and morphological properties of the nanofibers. The Brunauer–Emmett–Teller surface area of the nanofiber membranes was very high (46.6–149.2 m(2)/g) and decreased with increasing calcination temperature as expected. Photocatalytic activity investigations were determined using methylene blue (MB) as a model dye under UV and sunlight irradiation. High degradation performances were achieved with the calcination temperatures of 650 and 750 °C because of the high specific surface area and the anatase structure of the nanofiber membranes. Moreover, the ceramic membranes showed antibacterial activity against Escherichia coli as a Gram-negative bacterium and Staphylococcus aureus as a Gram-positive bacterium. The superior properties of the novel TiO(2)-based multi-oxide nanofiber membranes proved as a promising candidate for various industries, especially the removal of textile dyes from wastewater.
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spelling pubmed-100615262023-03-31 Photocatalytic and Antimicrobial Properties of Electrospun TiO(2)–SiO(2)–Al(2)O(3)–ZrO(2)–CaO–CeO(2) Ceramic Membranes Yerli Soylu, Nuray Soylu, Anıl Dikmetas, Dilara Nur Karbancioglu-Guler, Funda Kucukbayrak, Sadriye Erol Taygun, Melek ACS Omega [Image: see text] In this study, TiO(2)-based ceramic nanofiber membranes in the system of TiO(2)–SiO(2)–Al(2)O(3)–ZrO(2)–CaO–CeO(2) were synthesized by combining sol–gel and electrospinning processes. In order to investigate the thermal treatment temperature effect, the obtained nanofiber membranes were calcined at different temperatures ranging from 550 to 850 °C. Different characterization methods such as X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared (FT-IR), and high-resolution transmission electron microscopy (HR-TEM) were conducted on the obtained membranes to investigate the structural and morphological properties of the nanofibers. The Brunauer–Emmett–Teller surface area of the nanofiber membranes was very high (46.6–149.2 m(2)/g) and decreased with increasing calcination temperature as expected. Photocatalytic activity investigations were determined using methylene blue (MB) as a model dye under UV and sunlight irradiation. High degradation performances were achieved with the calcination temperatures of 650 and 750 °C because of the high specific surface area and the anatase structure of the nanofiber membranes. Moreover, the ceramic membranes showed antibacterial activity against Escherichia coli as a Gram-negative bacterium and Staphylococcus aureus as a Gram-positive bacterium. The superior properties of the novel TiO(2)-based multi-oxide nanofiber membranes proved as a promising candidate for various industries, especially the removal of textile dyes from wastewater. American Chemical Society 2023-03-17 /pmc/articles/PMC10061526/ /pubmed/37008115 http://dx.doi.org/10.1021/acsomega.2c06986 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Yerli Soylu, Nuray
Soylu, Anıl
Dikmetas, Dilara Nur
Karbancioglu-Guler, Funda
Kucukbayrak, Sadriye
Erol Taygun, Melek
Photocatalytic and Antimicrobial Properties of Electrospun TiO(2)–SiO(2)–Al(2)O(3)–ZrO(2)–CaO–CeO(2) Ceramic Membranes
title Photocatalytic and Antimicrobial Properties of Electrospun TiO(2)–SiO(2)–Al(2)O(3)–ZrO(2)–CaO–CeO(2) Ceramic Membranes
title_full Photocatalytic and Antimicrobial Properties of Electrospun TiO(2)–SiO(2)–Al(2)O(3)–ZrO(2)–CaO–CeO(2) Ceramic Membranes
title_fullStr Photocatalytic and Antimicrobial Properties of Electrospun TiO(2)–SiO(2)–Al(2)O(3)–ZrO(2)–CaO–CeO(2) Ceramic Membranes
title_full_unstemmed Photocatalytic and Antimicrobial Properties of Electrospun TiO(2)–SiO(2)–Al(2)O(3)–ZrO(2)–CaO–CeO(2) Ceramic Membranes
title_short Photocatalytic and Antimicrobial Properties of Electrospun TiO(2)–SiO(2)–Al(2)O(3)–ZrO(2)–CaO–CeO(2) Ceramic Membranes
title_sort photocatalytic and antimicrobial properties of electrospun tio(2)–sio(2)–al(2)o(3)–zro(2)–cao–ceo(2) ceramic membranes
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10061526/
https://www.ncbi.nlm.nih.gov/pubmed/37008115
http://dx.doi.org/10.1021/acsomega.2c06986
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