Cargando…
Photocatalytic and Antimicrobial Properties of Electrospun TiO(2)–SiO(2)–Al(2)O(3)–ZrO(2)–CaO–CeO(2) Ceramic Membranes
[Image: see text] In this study, TiO(2)-based ceramic nanofiber membranes in the system of TiO(2)–SiO(2)–Al(2)O(3)–ZrO(2)–CaO–CeO(2) were synthesized by combining sol–gel and electrospinning processes. In order to investigate the thermal treatment temperature effect, the obtained nanofiber membranes...
Autores principales: | , , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10061526/ https://www.ncbi.nlm.nih.gov/pubmed/37008115 http://dx.doi.org/10.1021/acsomega.2c06986 |
_version_ | 1785017312054607872 |
---|---|
author | Yerli Soylu, Nuray Soylu, Anıl Dikmetas, Dilara Nur Karbancioglu-Guler, Funda Kucukbayrak, Sadriye Erol Taygun, Melek |
author_facet | Yerli Soylu, Nuray Soylu, Anıl Dikmetas, Dilara Nur Karbancioglu-Guler, Funda Kucukbayrak, Sadriye Erol Taygun, Melek |
author_sort | Yerli Soylu, Nuray |
collection | PubMed |
description | [Image: see text] In this study, TiO(2)-based ceramic nanofiber membranes in the system of TiO(2)–SiO(2)–Al(2)O(3)–ZrO(2)–CaO–CeO(2) were synthesized by combining sol–gel and electrospinning processes. In order to investigate the thermal treatment temperature effect, the obtained nanofiber membranes were calcined at different temperatures ranging from 550 to 850 °C. Different characterization methods such as X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared (FT-IR), and high-resolution transmission electron microscopy (HR-TEM) were conducted on the obtained membranes to investigate the structural and morphological properties of the nanofibers. The Brunauer–Emmett–Teller surface area of the nanofiber membranes was very high (46.6–149.2 m(2)/g) and decreased with increasing calcination temperature as expected. Photocatalytic activity investigations were determined using methylene blue (MB) as a model dye under UV and sunlight irradiation. High degradation performances were achieved with the calcination temperatures of 650 and 750 °C because of the high specific surface area and the anatase structure of the nanofiber membranes. Moreover, the ceramic membranes showed antibacterial activity against Escherichia coli as a Gram-negative bacterium and Staphylococcus aureus as a Gram-positive bacterium. The superior properties of the novel TiO(2)-based multi-oxide nanofiber membranes proved as a promising candidate for various industries, especially the removal of textile dyes from wastewater. |
format | Online Article Text |
id | pubmed-10061526 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-100615262023-03-31 Photocatalytic and Antimicrobial Properties of Electrospun TiO(2)–SiO(2)–Al(2)O(3)–ZrO(2)–CaO–CeO(2) Ceramic Membranes Yerli Soylu, Nuray Soylu, Anıl Dikmetas, Dilara Nur Karbancioglu-Guler, Funda Kucukbayrak, Sadriye Erol Taygun, Melek ACS Omega [Image: see text] In this study, TiO(2)-based ceramic nanofiber membranes in the system of TiO(2)–SiO(2)–Al(2)O(3)–ZrO(2)–CaO–CeO(2) were synthesized by combining sol–gel and electrospinning processes. In order to investigate the thermal treatment temperature effect, the obtained nanofiber membranes were calcined at different temperatures ranging from 550 to 850 °C. Different characterization methods such as X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared (FT-IR), and high-resolution transmission electron microscopy (HR-TEM) were conducted on the obtained membranes to investigate the structural and morphological properties of the nanofibers. The Brunauer–Emmett–Teller surface area of the nanofiber membranes was very high (46.6–149.2 m(2)/g) and decreased with increasing calcination temperature as expected. Photocatalytic activity investigations were determined using methylene blue (MB) as a model dye under UV and sunlight irradiation. High degradation performances were achieved with the calcination temperatures of 650 and 750 °C because of the high specific surface area and the anatase structure of the nanofiber membranes. Moreover, the ceramic membranes showed antibacterial activity against Escherichia coli as a Gram-negative bacterium and Staphylococcus aureus as a Gram-positive bacterium. The superior properties of the novel TiO(2)-based multi-oxide nanofiber membranes proved as a promising candidate for various industries, especially the removal of textile dyes from wastewater. American Chemical Society 2023-03-17 /pmc/articles/PMC10061526/ /pubmed/37008115 http://dx.doi.org/10.1021/acsomega.2c06986 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Yerli Soylu, Nuray Soylu, Anıl Dikmetas, Dilara Nur Karbancioglu-Guler, Funda Kucukbayrak, Sadriye Erol Taygun, Melek Photocatalytic and Antimicrobial Properties of Electrospun TiO(2)–SiO(2)–Al(2)O(3)–ZrO(2)–CaO–CeO(2) Ceramic Membranes |
title | Photocatalytic
and Antimicrobial Properties of Electrospun
TiO(2)–SiO(2)–Al(2)O(3)–ZrO(2)–CaO–CeO(2) Ceramic
Membranes |
title_full | Photocatalytic
and Antimicrobial Properties of Electrospun
TiO(2)–SiO(2)–Al(2)O(3)–ZrO(2)–CaO–CeO(2) Ceramic
Membranes |
title_fullStr | Photocatalytic
and Antimicrobial Properties of Electrospun
TiO(2)–SiO(2)–Al(2)O(3)–ZrO(2)–CaO–CeO(2) Ceramic
Membranes |
title_full_unstemmed | Photocatalytic
and Antimicrobial Properties of Electrospun
TiO(2)–SiO(2)–Al(2)O(3)–ZrO(2)–CaO–CeO(2) Ceramic
Membranes |
title_short | Photocatalytic
and Antimicrobial Properties of Electrospun
TiO(2)–SiO(2)–Al(2)O(3)–ZrO(2)–CaO–CeO(2) Ceramic
Membranes |
title_sort | photocatalytic
and antimicrobial properties of electrospun
tio(2)–sio(2)–al(2)o(3)–zro(2)–cao–ceo(2) ceramic
membranes |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10061526/ https://www.ncbi.nlm.nih.gov/pubmed/37008115 http://dx.doi.org/10.1021/acsomega.2c06986 |
work_keys_str_mv | AT yerlisoylunuray photocatalyticandantimicrobialpropertiesofelectrospuntio2sio2al2o3zro2caoceo2ceramicmembranes AT soyluanıl photocatalyticandantimicrobialpropertiesofelectrospuntio2sio2al2o3zro2caoceo2ceramicmembranes AT dikmetasdilaranur photocatalyticandantimicrobialpropertiesofelectrospuntio2sio2al2o3zro2caoceo2ceramicmembranes AT karbancioglugulerfunda photocatalyticandantimicrobialpropertiesofelectrospuntio2sio2al2o3zro2caoceo2ceramicmembranes AT kucukbayraksadriye photocatalyticandantimicrobialpropertiesofelectrospuntio2sio2al2o3zro2caoceo2ceramicmembranes AT eroltaygunmelek photocatalyticandantimicrobialpropertiesofelectrospuntio2sio2al2o3zro2caoceo2ceramicmembranes |